Stabilization of Ruthenium(II) Polypyridyl Chromophores on Nanoparticle Metal-Oxide Electrodes in Water by Hydrophobic PMMA Overlayers

We describe a poly­(methyl methacrylate) (PMMA) dip-coating procedure, which results in surface stabilization of phosphonate and carboxylate derivatives of Ru­(II)-polypyridyl complexes surface-bound to mesoporous nanoparticle TiO2 and nanoITO films in aqueous solutions. As shown by contact angle an...

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Veröffentlicht in:	J. Am. Chem. Soc 2014-10, Vol.136 (39), p.13514-13517
Hauptverfasser:	Wee, Kyung-Ryang, Brennaman, M. Kyle, Alibabaei, Leila, Farnum, Byron H, Sherman, Benjamin, Lapides, Alexander M, Meyer, Thomas J
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), hydrogen and fuel cells, electrodes - solar, charge transport, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)
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