Enhanced Photochemical Hydrogen Evolution from Fe4S4‑Based Biomimetic Chalcogels Containing M2+ (M = Pt, Zn, Co, Ni, Sn) Centers

Naturally abundant enzymes often feature active sites comprising transition metal cluster units that catalyze chemical processes and reduce small molecules as well as protons. We introduce a family of new chalcogenide aerogels (chalcogels), aiming to model the function of active sites and the struct...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2014-09, Vol.136 (38), p.13371-13380
Hauptverfasser:	Shim, Yurina, Young, Ryan M, Douvalis, Alexios P, Dyar, Scott M, Yuhas, Benjamin D, Bakas, Thomas, Wasielewski, Michael R, Kanatzidis, Mercouri G
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemistry Biomimetics Catalysis catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar (fuels), photosynthesis (natural and artificial), bio-inspired, hydrogen and fuel cells, electrodes - solar, defects, charge transport, spin dynamics, membrane, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) Gels - chemistry Hydrogen - chemistry Iron Compounds - chemistry Metals - chemistry Models, Molecular Oxidation-Reduction Photochemical Processes Porosity Spectroscopy, Mossbauer Sulfur Compounds - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!