A successive-reaction nanoreactor made of active molecularly imprinted polymer containing Ag nanoparticles
A successive-reaction nanoreactor made of a unique molecularly imprinted polymer containing Ag nanoparticles is reported. This molecularly imprinted polymer was fabricated using two well-coupled templates, i.e., 4-nitrophenyl acetate and 4-nitrophenol. The catalytic hydrolysis of the former by this...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2013-01, Vol.1 (47), p.15102-15109 |
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| Sprache: | eng |
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| container_end_page | 15109 |
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| container_issue | 47 |
| container_start_page | 15102 |
| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
| container_volume | 1 |
| creator | Li, Songjun Luo, Yiyun Whitcombe, Michael J. Piletsky, Sergey A. |
| description | A successive-reaction nanoreactor made of a unique molecularly imprinted polymer containing Ag nanoparticles is reported. This molecularly imprinted polymer was fabricated using two well-coupled templates, i.e., 4-nitrophenyl acetate and 4-nitrophenol. The catalytic hydrolysis of the former by this nanoreactor led to the formation of the latter, which was further reduced by the nanoreactor to 4-aminophenol. Unlike reported nanoreactors, which usually promote one single reaction, this novel nanoreactor can run cascade reactions. The proposed integration of active molecularly imprinted polymers with metal nanoparticles opens a new opportunity for creating functional catalysts for complicated chemical processes. |
| doi_str_mv | 10.1039/c3ta13454g |
| format | Article |
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This molecularly imprinted polymer was fabricated using two well-coupled templates, i.e., 4-nitrophenyl acetate and 4-nitrophenol. The catalytic hydrolysis of the former by this nanoreactor led to the formation of the latter, which was further reduced by the nanoreactor to 4-aminophenol. Unlike reported nanoreactors, which usually promote one single reaction, this novel nanoreactor can run cascade reactions. The proposed integration of active molecularly imprinted polymers with metal nanoparticles opens a new opportunity for creating functional catalysts for complicated chemical processes.</abstract><doi>10.1039/c3ta13454g</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2013-01, Vol.1 (47), p.15102-15109 |
| issn | 2050-7488 2050-7496 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1562673040 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A successive-reaction nanoreactor made of active molecularly imprinted polymer containing Ag nanoparticles |
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