Quantum Chemistry Guide to PTRMS Studies of As-Yet Undetected Products of the Bromine-Atom Initiated Oxidation of Gaseous Elemental Mercury

A series of BrHgY compounds (Y = NO2, ClO, BrO, HOO, etc.) are expected to be formed in the Br-initiated oxidation of Hg(0) to Hg(II) in the atmosphere. These BrHgY compounds have not yet been reported in any experiment. This article investigates the potential to use proton-transfer reaction mass sp...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2014-09, Vol.118 (36), p.7847-7854
Hauptverfasser:	Dibble, Theodore S, Zelie, Matthew J, Jiao, Yuge
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Pollutants - analysis Air Pollutants - chemistry Bromides - chemistry Energy Transfer Mass Spectrometry - methods Mercury - analysis Mercury - chemistry Mercury Compounds - chemistry Models, Chemical Oxidation-Reduction Protons Quantum Theory Volatilization
Online-Zugang:	Volltext
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