Synergistic Rhodium(II) Carboxylate and Brønsted Acid Catalyzed Multicomponent Reactions of Enalcarbenoids: Direct Synthesis of α‑Pyrrolylbenzylamines

The design of a synergistic rhodium­(II) carboxylate and BINOL phosphoric acid catalyzed efficient multicomponent reaction of enaldiazo compounds, arylamines, and aryl aldehydes leading to the first transition-metal-catalyzed direct synthesis of valuable α-pyrrolylbenzylamines is disclosed. The reac...

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Veröffentlicht in:	Organic letters 2014-07, Vol.16 (14), p.3700-3703
Hauptverfasser:	Dawande, Sudam Ganpat, Kanchupalli, Vinaykumar, Lad, Bapurao Sudam, Rai, Jyoti, Katukojvala, Sreenivas
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes - chemistry Benzylamines - chemical synthesis Benzylamines - chemistry Carboxylic Acids - chemistry Catalysis Molecular Structure Phosphoric Acids - chemistry Pyrroles - chemical synthesis Pyrroles - chemistry Rhodium - chemistry Stereoisomerism
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