Mammalian exocrine secretions : X. Constituents of preorbital secretion of grysbok, Raphicerus melanotis

Using electron impact and chemical ionization mass spectrometry with methane and nitric oxide as reactant gases in conjunction with mass spectral analysis of the dimethyl disulfide derivatives of unsaturated constituents, 51 compounds have been identified in addition to the compounds previously foun...

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Veröffentlicht in:	Journal of chemical ecology 1996-04, Vol.22 (4), p.739-764
Hauptverfasser:	BURGER, B. V, TIEN, F.-C, LE ROUX, M, MO, W.-P
Format:	Artikel
Sprache:	eng
Schlagworte:	Animal and plant ecology Animal, plant and microbial ecology Animals Autoecology Biological and medical sciences Fundamental and applied biological sciences. Psychology Mammalia Vertebrata
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description	Using electron impact and chemical ionization mass spectrometry with methane and nitric oxide as reactant gases in conjunction with mass spectral analysis of the dimethyl disulfide derivatives of unsaturated constituents, 51 compounds have been identified in addition to the compounds previously found in the preorbital secretion of the grysbokRaphicerus melanotis. The compounds identified are saturated, monounsaturated, and diunsaturated alcohols and formates, saturated and monounsaturated aldehydes, saturated carboxylic acids,γ- andδ-lactones, alkyl methyl sulfides, andβ-hydroxyalkyl acetates. All of these compounds have unbranched structures. The constituent previously incorrectly identified as (Z)-5-tetradecen-1-ol, was found to consist of the coeluting (Z)-7- and (Z)-8-tetradecenols.
doi_str_mv	10.1007/BF02033583
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Constituents of preorbital secretion of grysbok, Raphicerus melanotis</atitle><jtitle>Journal of chemical ecology</jtitle><addtitle>J Chem Ecol</addtitle><date>1996-04</date><risdate>1996</risdate><volume>22</volume><issue>4</issue><spage>739</spage><epage>764</epage><pages>739-764</pages><issn>0098-0331</issn><eissn>1573-1561</eissn><coden>JCECD8</coden><abstract>Using electron impact and chemical ionization mass spectrometry with methane and nitric oxide as reactant gases in conjunction with mass spectral analysis of the dimethyl disulfide derivatives of unsaturated constituents, 51 compounds have been identified in addition to the compounds previously found in the preorbital secretion of the grysbokRaphicerus melanotis. The compounds identified are saturated, monounsaturated, and diunsaturated alcohols and formates, saturated and monounsaturated aldehydes, saturated carboxylic acids,γ- andδ-lactones, alkyl methyl sulfides, andβ-hydroxyalkyl acetates. 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subjects	Animal and plant ecology Animal, plant and microbial ecology Animals Autoecology Biological and medical sciences Fundamental and applied biological sciences. Psychology Mammalia Vertebrata
title	Mammalian exocrine secretions : X. Constituents of preorbital secretion of grysbok, Raphicerus melanotis
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