Construction of Hybrid Porous Materials from Cubic Octavinylsilsesquioxane through Friedel-Crafts Reaction Using Tetraphenylsilane as a Concentrative Crosslinker
A series of novel hybrid porous polymers (HPPs), derived from cubic octavinylsilsesquioxane (OVS; [(C2H3SiO1.5)8]) and tetraphenylsilane (TPS), were successfully synthesized through Friedel–Crafts alkylation reaction. The porosities of the HPPs could be tuned by modulating the molar ratio of OVS and...
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| Veröffentlicht in: | European journal of inorganic chemistry 2014-06, Vol.2014 (18), p.2976-2982 |
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| container_title | European journal of inorganic chemistry |
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| creator | Yang, Wenyan Wang, Dengxu Li, Liguo Liu, Hongzhi |
| description | A series of novel hybrid porous polymers (HPPs), derived from cubic octavinylsilsesquioxane (OVS; [(C2H3SiO1.5)8]) and tetraphenylsilane (TPS), were successfully synthesized through Friedel–Crafts alkylation reaction. The porosities of the HPPs could be tuned by modulating the molar ratio of OVS and TPS. The HPPs showed high porosity, with Brunauer–Emmett–Teller specific surface areas of 518–989 m2 g–1, and total pore volumes of 0.35–0.76 cm3 g–1, as well as narrow pore‐size distributions. For gas sorption application, HPP‐5 possessed a hydrogen uptake of 0.80 wt.‐% at 760 Torr/77 K and a carbon dioxide uptake of 3.31 wt.‐% at 760 Torr/298 K.
Tetraphenylsilane was used as a concentrative crosslinker to react with octavinylsilsesquioxane through Friedel–Crafts reaction to prepare hybrid porous materials with tunable porosity. These materials are promising candidates for storing hydrogen and carbon dioxide. |
| doi_str_mv | 10.1002/ejic.201402156 |
| format | Article |
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Tetraphenylsilane was used as a concentrative crosslinker to react with octavinylsilsesquioxane through Friedel–Crafts reaction to prepare hybrid porous materials with tunable porosity. These materials are promising candidates for storing hydrogen and carbon dioxide.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.201402156</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alkylation ; Carbon dioxide ; Chemical synthesis ; Cross-coupling ; Crosslinking ; Friedel-Crafts reaction ; Gas storage ; Mesoporous materials ; Polymers ; Porosity ; Porous materials ; Silicon ; Sorption ; Uptakes</subject><ispartof>European journal of inorganic chemistry, 2014-06, Vol.2014 (18), p.2976-2982</ispartof><rights>Copyright © 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright Wiley Subscription Services, Inc. Jun 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5526-bc48d0124d3dfa5073cc779df5e5fd6e36617a7ab953b986d58a90a7526b48453</citedby><cites>FETCH-LOGICAL-c5526-bc48d0124d3dfa5073cc779df5e5fd6e36617a7ab953b986d58a90a7526b48453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.201402156$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.201402156$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27928,27929,45578,45579</link.rule.ids></links><search><creatorcontrib>Yang, Wenyan</creatorcontrib><creatorcontrib>Wang, Dengxu</creatorcontrib><creatorcontrib>Li, Liguo</creatorcontrib><creatorcontrib>Liu, Hongzhi</creatorcontrib><title>Construction of Hybrid Porous Materials from Cubic Octavinylsilsesquioxane through Friedel-Crafts Reaction Using Tetraphenylsilane as a Concentrative Crosslinker</title><title>European journal of inorganic chemistry</title><addtitle>Eur. J. Inorg. Chem</addtitle><description>A series of novel hybrid porous polymers (HPPs), derived from cubic octavinylsilsesquioxane (OVS; [(C2H3SiO1.5)8]) and tetraphenylsilane (TPS), were successfully synthesized through Friedel–Crafts alkylation reaction. The porosities of the HPPs could be tuned by modulating the molar ratio of OVS and TPS. The HPPs showed high porosity, with Brunauer–Emmett–Teller specific surface areas of 518–989 m2 g–1, and total pore volumes of 0.35–0.76 cm3 g–1, as well as narrow pore‐size distributions. For gas sorption application, HPP‐5 possessed a hydrogen uptake of 0.80 wt.‐% at 760 Torr/77 K and a carbon dioxide uptake of 3.31 wt.‐% at 760 Torr/298 K.
Tetraphenylsilane was used as a concentrative crosslinker to react with octavinylsilsesquioxane through Friedel–Crafts reaction to prepare hybrid porous materials with tunable porosity. These materials are promising candidates for storing hydrogen and carbon dioxide.</description><subject>Alkylation</subject><subject>Carbon dioxide</subject><subject>Chemical synthesis</subject><subject>Cross-coupling</subject><subject>Crosslinking</subject><subject>Friedel-Crafts reaction</subject><subject>Gas storage</subject><subject>Mesoporous materials</subject><subject>Polymers</subject><subject>Porosity</subject><subject>Porous materials</subject><subject>Silicon</subject><subject>Sorption</subject><subject>Uptakes</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhSMEEqWwZW2JDZsMdvwXL1Ho9EeFItQWdpbj3HQ8zcRT22k7j8Ob4lFQhVjAypb8fVfn-hTFW4IXBOPqA6ydXVSYMFwRLp4VBwQrVWJRV8_znVFWEsXql8WrGNcYY4qpOCh-Nn6MKUw2OT8i36OTXRtch7764KeIPpsEwZkhoj74DWqm1ll0YZO5d-NuiG6IEO8m5x_NCCitsnOzQsvgoIOhbILpU0TfwMzTr6Ibb9AlpGC2K5j9vWciMijnsDDmp-TuATXBxzi48RbC6-JFnwPAm9_nYXG1PLpsTsrzi-PT5uN5aTmvRNlaVneYVKyjXW84ltRaKVXXc-B9J4AKQaSRplWctqoWHa-NwkZmt2U14_SweD_P3QZ_N0FMeuOihWEfMX-FJpwrSbmUdUbf_YWu_RTGnE5TXEvGKiXEvyjCmVJC8ZplajFTdr9ygF5vg9uYsNME632vet-rfuo1C2oWHtwAu__Q-ujstPnTLWfXxQSPT64Jt1pIKrn-_uVY00_XPwi-Xuoz-gtGA7kB</recordid><startdate>201406</startdate><enddate>201406</enddate><creator>Yang, Wenyan</creator><creator>Wang, Dengxu</creator><creator>Li, Liguo</creator><creator>Liu, Hongzhi</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7TB</scope><scope>FR3</scope></search><sort><creationdate>201406</creationdate><title>Construction of Hybrid Porous Materials from Cubic Octavinylsilsesquioxane through Friedel-Crafts Reaction Using Tetraphenylsilane as a Concentrative Crosslinker</title><author>Yang, Wenyan ; Wang, Dengxu ; Li, Liguo ; Liu, Hongzhi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5526-bc48d0124d3dfa5073cc779df5e5fd6e36617a7ab953b986d58a90a7526b48453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Alkylation</topic><topic>Carbon dioxide</topic><topic>Chemical synthesis</topic><topic>Cross-coupling</topic><topic>Crosslinking</topic><topic>Friedel-Crafts reaction</topic><topic>Gas storage</topic><topic>Mesoporous materials</topic><topic>Polymers</topic><topic>Porosity</topic><topic>Porous materials</topic><topic>Silicon</topic><topic>Sorption</topic><topic>Uptakes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Wenyan</creatorcontrib><creatorcontrib>Wang, Dengxu</creatorcontrib><creatorcontrib>Li, Liguo</creatorcontrib><creatorcontrib>Liu, Hongzhi</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Engineering Research Database</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Wenyan</au><au>Wang, Dengxu</au><au>Li, Liguo</au><au>Liu, Hongzhi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Construction of Hybrid Porous Materials from Cubic Octavinylsilsesquioxane through Friedel-Crafts Reaction Using Tetraphenylsilane as a Concentrative Crosslinker</atitle><jtitle>European journal of inorganic chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2014-06</date><risdate>2014</risdate><volume>2014</volume><issue>18</issue><spage>2976</spage><epage>2982</epage><pages>2976-2982</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>A series of novel hybrid porous polymers (HPPs), derived from cubic octavinylsilsesquioxane (OVS; [(C2H3SiO1.5)8]) and tetraphenylsilane (TPS), were successfully synthesized through Friedel–Crafts alkylation reaction. The porosities of the HPPs could be tuned by modulating the molar ratio of OVS and TPS. The HPPs showed high porosity, with Brunauer–Emmett–Teller specific surface areas of 518–989 m2 g–1, and total pore volumes of 0.35–0.76 cm3 g–1, as well as narrow pore‐size distributions. For gas sorption application, HPP‐5 possessed a hydrogen uptake of 0.80 wt.‐% at 760 Torr/77 K and a carbon dioxide uptake of 3.31 wt.‐% at 760 Torr/298 K.
Tetraphenylsilane was used as a concentrative crosslinker to react with octavinylsilsesquioxane through Friedel–Crafts reaction to prepare hybrid porous materials with tunable porosity. These materials are promising candidates for storing hydrogen and carbon dioxide.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.201402156</doi><tpages>7</tpages></addata></record> |
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| subjects | Alkylation Carbon dioxide Chemical synthesis Cross-coupling Crosslinking Friedel-Crafts reaction Gas storage Mesoporous materials Polymers Porosity Porous materials Silicon Sorption Uptakes |
| title | Construction of Hybrid Porous Materials from Cubic Octavinylsilsesquioxane through Friedel-Crafts Reaction Using Tetraphenylsilane as a Concentrative Crosslinker |
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