Dimer ion formation and intermolecular fragmentation of 1,2-diacylglycerols revealed by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry for more comprehensive lipid analysis

RATIONALE The ionization of neutral diacylglycerols (DAGs) by electrospray ionization mass spectrometry (ESI‐MS) is challenging compared with other lipid classes which possess ionic head group conjugations. Although ESI‐MS is the method of choice in lipidomic analysis, it is questionable whether all...

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Veröffentlicht in:	Rapid communications in mass spectrometry 2014-08, Vol.28 (15), p.1735-1744
Hauptverfasser:	Müller, Constanze, Kanawati, Basem, Rock, Theresa M., Forcisi, Sara, Moritz, Franco, Schmitt-Kopplin, Philippe
Format:	Artikel
Sprache:	eng
Schlagworte:	Computer Simulation Cyclotron resonance Cyclotrons Diglycerides - analysis Diglycerides - chemistry Dimerization Dimers Fourier transforms Fragmentation Ionization Ions - chemical synthesis Lipids Mass spectrometry Mathematical analysis Models, Chemical Spectrometry, Mass, Electrospray Ionization - methods Spectroscopy, Fourier Transform Infrared - methods
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