Controllable Synthesis of Hollow Si Anode for Long-Cycle-Life Lithium-Ion Batteries

A versatile and surfactant‐free method is developed to synthesize hollow Si materials using carbonates as templates without the use of hazardous hydrofluoric acid. The morphology of Si is controllable from hollow cubes, spheres, and tubes, to flowers and other shapes. Such hollow Si materials as ano...

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Veröffentlicht in:Advanced materials (Weinheim) 2014-07, Vol.26 (25), p.4326-4332
Hauptverfasser: Huang, Xingkang, Yang, Joseph, Mao, Shun, Chang, Jingbo, Hallac, Peter B., Fell, Christopher R., Metz, Bernhard, Jiang, Junwei, Hurley, Patrick T., Chen, Junhong
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container_end_page 4332
container_issue 25
container_start_page 4326
container_title Advanced materials (Weinheim)
container_volume 26
creator Huang, Xingkang
Yang, Joseph
Mao, Shun
Chang, Jingbo
Hallac, Peter B.
Fell, Christopher R.
Metz, Bernhard
Jiang, Junwei
Hurley, Patrick T.
Chen, Junhong
description A versatile and surfactant‐free method is developed to synthesize hollow Si materials using carbonates as templates without the use of hazardous hydrofluoric acid. The morphology of Si is controllable from hollow cubes, spheres, and tubes, to flowers and other shapes. Such hollow Si materials as anodes of lithium‐ion batteries show excellent cyclic performance, which is promising for practical applications.
doi_str_mv 10.1002/adma.201400578
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source Wiley Online Library Journals Frontfile Complete
subjects Anodes
Carbonates
hollow materials
Hydrofluoric acid
Lithium-ion batteries
Silicon
Stability
Synthesis
Tubes
title Controllable Synthesis of Hollow Si Anode for Long-Cycle-Life Lithium-Ion Batteries
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