Development and evaluation of oil in water nanoemulsions based on polyether silicone as demulsifier and antifoam agents for petroleum
ABSTRACT Oil in water (o/w) nanoemulsions were synthesized in order to be evaluated as an alternative to petroleum emulsions destabilization processes and inhibition of foam formed in the crude oil. The nanoemulsions were prepared by the high energy method through High Pressure Homogenizer (HPH), ut...
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| Veröffentlicht in: | Journal of applied polymer science 2014-10, Vol.131 (20), p.np-n/a |
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| creator | Fraga, Assis K. Souza, Luiz F. I. Magalhães, Jeniffer Rayane Mansur, Claudia R. E. |
| description | ABSTRACT
Oil in water (o/w) nanoemulsions were synthesized in order to be evaluated as an alternative to petroleum emulsions destabilization processes and inhibition of foam formed in the crude oil. The nanoemulsions were prepared by the high energy method through High Pressure Homogenizer (HPH), utilizing poly(propylene glycol) (PPG) and xylene solvent as oil phase and different polarity polyether silicone surfactants samples. These nanoemulsions were evaluated in respect to their efficiency in the petroleum demulsification process. The results of these tests showed that nanoemulsions performance on the destabilization of petroleum emulsions is influenced by the utilized surfactant's polarity. The nanoemulsions and pure samples of PPG and xylene solvent were evaluated concerning capacity of formed foam inhibition in petroleum (antifoam test), and the results showed no significant influence of samples on foam stability. Petroleum/saline water added interfacial tension measurements, added or not the nanoemulsions were executed and showed that the additives adsorption in the interface is related to the surfactant's polarity and nanoemulsion drop size. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40889. |
| doi_str_mv | 10.1002/app.40889 |
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Oil in water (o/w) nanoemulsions were synthesized in order to be evaluated as an alternative to petroleum emulsions destabilization processes and inhibition of foam formed in the crude oil. The nanoemulsions were prepared by the high energy method through High Pressure Homogenizer (HPH), utilizing poly(propylene glycol) (PPG) and xylene solvent as oil phase and different polarity polyether silicone surfactants samples. These nanoemulsions were evaluated in respect to their efficiency in the petroleum demulsification process. The results of these tests showed that nanoemulsions performance on the destabilization of petroleum emulsions is influenced by the utilized surfactant's polarity. The nanoemulsions and pure samples of PPG and xylene solvent were evaluated concerning capacity of formed foam inhibition in petroleum (antifoam test), and the results showed no significant influence of samples on foam stability. Petroleum/saline water added interfacial tension measurements, added or not the nanoemulsions were executed and showed that the additives adsorption in the interface is related to the surfactant's polarity and nanoemulsion drop size. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40889.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.40889</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken, NJ: Blackwell Publishing Ltd</publisher><subject>Applied sciences ; copolymers ; Crude oil ; Destabilization ; Exact sciences and technology ; Foams ; Inhibition ; Inorganic and organomineral polymers ; Materials science ; micelles ; Nanoemulsions ; Nanostructure ; oil & gas ; Physicochemistry of polymers ; Polarity ; Polymers ; Properties and characterization ; Solvents ; surfactants ; Xylene</subject><ispartof>Journal of applied polymer science, 2014-10, Vol.131 (20), p.np-n/a</ispartof><rights>2014 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4359-d23701c9996ff54c190bd8d62869b68c81366403bdd73444d4302d65e214646b3</citedby><cites>FETCH-LOGICAL-c4359-d23701c9996ff54c190bd8d62869b68c81366403bdd73444d4302d65e214646b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.40889$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.40889$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28691150$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Fraga, Assis K.</creatorcontrib><creatorcontrib>Souza, Luiz F. I.</creatorcontrib><creatorcontrib>Magalhães, Jeniffer Rayane</creatorcontrib><creatorcontrib>Mansur, Claudia R. E.</creatorcontrib><title>Development and evaluation of oil in water nanoemulsions based on polyether silicone as demulsifier and antifoam agents for petroleum</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
Oil in water (o/w) nanoemulsions were synthesized in order to be evaluated as an alternative to petroleum emulsions destabilization processes and inhibition of foam formed in the crude oil. The nanoemulsions were prepared by the high energy method through High Pressure Homogenizer (HPH), utilizing poly(propylene glycol) (PPG) and xylene solvent as oil phase and different polarity polyether silicone surfactants samples. These nanoemulsions were evaluated in respect to their efficiency in the petroleum demulsification process. The results of these tests showed that nanoemulsions performance on the destabilization of petroleum emulsions is influenced by the utilized surfactant's polarity. The nanoemulsions and pure samples of PPG and xylene solvent were evaluated concerning capacity of formed foam inhibition in petroleum (antifoam test), and the results showed no significant influence of samples on foam stability. Petroleum/saline water added interfacial tension measurements, added or not the nanoemulsions were executed and showed that the additives adsorption in the interface is related to the surfactant's polarity and nanoemulsion drop size. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40889.</description><subject>Applied sciences</subject><subject>copolymers</subject><subject>Crude oil</subject><subject>Destabilization</subject><subject>Exact sciences and technology</subject><subject>Foams</subject><subject>Inhibition</subject><subject>Inorganic and organomineral polymers</subject><subject>Materials science</subject><subject>micelles</subject><subject>Nanoemulsions</subject><subject>Nanostructure</subject><subject>oil & gas</subject><subject>Physicochemistry of polymers</subject><subject>Polarity</subject><subject>Polymers</subject><subject>Properties and characterization</subject><subject>Solvents</subject><subject>surfactants</subject><subject>Xylene</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp1kc1u1DAURiMEEkNhwRtYQkiwSGvHP4mXVQst0gBdQFlajn0DLo4d7KTtPEDfGw8pXSCxsuR7vmNffVX1kuBDgnFzpKfpkOGuk4-qDcGyrZlousfVpsxI3UnJn1bPcr7CmBCOxaa6O4Vr8HEaIcxIB4vgWvtFzy4GFAcUnUcuoBs9Q0JBhwjj4nMZZtTrDBYVbIp-B_OPAmTnnYkBkM7IruTgyv3eq8PshqhHpL-XpzIaYkITzCl6WMbn1ZNB-wwv7s-D6uv7d19Ozuvt57MPJ8fb2jDKZW0b2mJipJRiGDgzROLedrZsKGQvOtMRKgTDtLe2pYwxyyhurODQECaY6OlB9Wb1Tin-WiDPanTZgPc6QFyyIpxL0TUdbwv66h_0Ki4plN8VigkiOceyUG9XyqSYc4JBTcmNOu0UwWpfiCqFqD-FFPb1vVFno_2QdDAuPwT2S-xLKdzRyt04D7v_C9XxxcVfc70mXJ7h9iGh008lWtpy9e3TmWov-cftubhUp_Q3LaCphA</recordid><startdate>20141015</startdate><enddate>20141015</enddate><creator>Fraga, Assis K.</creator><creator>Souza, Luiz F. I.</creator><creator>Magalhães, Jeniffer Rayane</creator><creator>Mansur, Claudia R. E.</creator><general>Blackwell Publishing Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20141015</creationdate><title>Development and evaluation of oil in water nanoemulsions based on polyether silicone as demulsifier and antifoam agents for petroleum</title><author>Fraga, Assis K. ; Souza, Luiz F. I. ; Magalhães, Jeniffer Rayane ; Mansur, Claudia R. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4359-d23701c9996ff54c190bd8d62869b68c81366403bdd73444d4302d65e214646b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>copolymers</topic><topic>Crude oil</topic><topic>Destabilization</topic><topic>Exact sciences and technology</topic><topic>Foams</topic><topic>Inhibition</topic><topic>Inorganic and organomineral polymers</topic><topic>Materials science</topic><topic>micelles</topic><topic>Nanoemulsions</topic><topic>Nanostructure</topic><topic>oil & gas</topic><topic>Physicochemistry of polymers</topic><topic>Polarity</topic><topic>Polymers</topic><topic>Properties and characterization</topic><topic>Solvents</topic><topic>surfactants</topic><topic>Xylene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fraga, Assis K.</creatorcontrib><creatorcontrib>Souza, Luiz F. I.</creatorcontrib><creatorcontrib>Magalhães, Jeniffer Rayane</creatorcontrib><creatorcontrib>Mansur, Claudia R. E.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fraga, Assis K.</au><au>Souza, Luiz F. I.</au><au>Magalhães, Jeniffer Rayane</au><au>Mansur, Claudia R. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development and evaluation of oil in water nanoemulsions based on polyether silicone as demulsifier and antifoam agents for petroleum</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2014-10-15</date><risdate>2014</risdate><volume>131</volume><issue>20</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
Oil in water (o/w) nanoemulsions were synthesized in order to be evaluated as an alternative to petroleum emulsions destabilization processes and inhibition of foam formed in the crude oil. The nanoemulsions were prepared by the high energy method through High Pressure Homogenizer (HPH), utilizing poly(propylene glycol) (PPG) and xylene solvent as oil phase and different polarity polyether silicone surfactants samples. These nanoemulsions were evaluated in respect to their efficiency in the petroleum demulsification process. The results of these tests showed that nanoemulsions performance on the destabilization of petroleum emulsions is influenced by the utilized surfactant's polarity. The nanoemulsions and pure samples of PPG and xylene solvent were evaluated concerning capacity of formed foam inhibition in petroleum (antifoam test), and the results showed no significant influence of samples on foam stability. Petroleum/saline water added interfacial tension measurements, added or not the nanoemulsions were executed and showed that the additives adsorption in the interface is related to the surfactant's polarity and nanoemulsion drop size. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40889.</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.40889</doi><tpages>9</tpages></addata></record> |
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| subjects | Applied sciences copolymers Crude oil Destabilization Exact sciences and technology Foams Inhibition Inorganic and organomineral polymers Materials science micelles Nanoemulsions Nanostructure oil & gas Physicochemistry of polymers Polarity Polymers Properties and characterization Solvents surfactants Xylene |
| title | Development and evaluation of oil in water nanoemulsions based on polyether silicone as demulsifier and antifoam agents for petroleum |
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