Reversible High-Capacity Si Nanocomposite Anodes for Lithium-ion Batteries Enabled by Molecular Layer Deposition
The molecular‐layer deposition of a flexible coating onto Si electrodes produces high‐capacity Si nanocomposite anodes. Using a reaction cascade based on inorganic trimethylaluminum and organic glycerol precursors, conventional nano‐Si electrodes undergo surface modifications, resulting in anodes th...
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| Veröffentlicht in: | Advanced Materials 2014-03, Vol.26 (10), p.1596-1601 |
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| container_title | Advanced Materials |
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| creator | Piper, Daniela Molina Travis, Jonathan J. Young, Matthias Son, Seoung-Bum Kim, Seul Cham Oh, Kyu Hwan George, Steven M. Ban, Chunmei Lee, Se-Hee |
| description | The molecular‐layer deposition of a flexible coating onto Si electrodes produces high‐capacity Si nanocomposite anodes. Using a reaction cascade based on inorganic trimethylaluminum and organic glycerol precursors, conventional nano‐Si electrodes undergo surface modifications, resulting in anodes that can be cycled over 100 times with capacities of nearly 900 mA h g−1 and Coulombic efficiencies in excess of 99%. |
| doi_str_mv | 10.1002/adma.201304714 |
| format | Article |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | alucone hybrid polymers Anodes Chemical and Material Sciences CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS Coated electrodes Deposition electrode materials Electrodes ENERGY STORAGE Glycerols Lithium-ion batteries MATERIALS SCIENCE molecular layer deposition Nanocomposites Nanostructure Precursors Silicon surface modification |
| title | Reversible High-Capacity Si Nanocomposite Anodes for Lithium-ion Batteries Enabled by Molecular Layer Deposition |
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