Optical and Electrochemical Combination Sensor with Poly-Aniline Film Modified Gold Surface and Its Application for Dissolved Oxygen Detection

Poly‐aniline (PAn) film can be oxidized by contacting oxygen in an electron‐transfer reaction and its redox state, for instance the open circuit potential and the dielectric constant, is quantitatively related to oxygen concentration. This feature may contribute to an improved application of dissolv...

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Veröffentlicht in:Electroanalysis (New York, N.Y.) N.Y.), 2014-02, Vol.26 (2), p.374-381
Hauptverfasser: Li, Meng, Liu, Wei, P.Correia, Jorge, Mourato, Ana C., Viana, Ana S., Jin, Gang
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container_end_page 381
container_issue 2
container_start_page 374
container_title Electroanalysis (New York, N.Y.)
container_volume 26
creator Li, Meng
Liu, Wei
P.Correia, Jorge
Mourato, Ana C.
Viana, Ana S.
Jin, Gang
description Poly‐aniline (PAn) film can be oxidized by contacting oxygen in an electron‐transfer reaction and its redox state, for instance the open circuit potential and the dielectric constant, is quantitatively related to oxygen concentration. This feature may contribute to an improved application of dissolved oxygen (DO) detection with the combined optical and electrochemical sensor. In this paper, PAn is used as a sensing surface to detect DO by the combination sensor composed of electrochemistry and total internal reflection imaging ellipsometry (EC‐TIRIE). Results demonstrate that both optical and electrical signals show a logarithmic correlation with DO concentration (0–20 ppm). Compared with the results obtained only with the gold surface, both the optical and electrical signals of the EC‐TIRIE sensor for DO detection are amplified with the PAn modified gold surface.
doi_str_mv 10.1002/elan.201300459
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source Wiley Online Library Journals Frontfile Complete
subjects Combined optical and electrochemical sensor
Dielectric constant
Dissolution
Dissolved oxygen
Electrochemistry
Ellipsometry
Gold
Open circuit potential
Optical communication
Poly-aniline
Reflection
Sensors
Total internal reflection imaging ellipsometry
title Optical and Electrochemical Combination Sensor with Poly-Aniline Film Modified Gold Surface and Its Application for Dissolved Oxygen Detection
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