Observation of the transition state for pressure-induced BO₃→BO₄ conversion in glass
A fundamental mechanistic understanding of the pressure- and/or temperature-induced facile transformation of the coordination environment of boron is important for changing the physical properties of glass. We have used in situ high-pressure (up to 2 gigapascals) boron-11 solid-state nuclear magneti...
Gespeichert in:
| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2014-08, Vol.345 (6200), p.1027-1029 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1029 |
|---|---|
| container_issue | 6200 |
| container_start_page | 1027 |
| container_title | Science (American Association for the Advancement of Science) |
| container_volume | 345 |
| creator | Edwards, Trenton Endo, Takatsugu Walton, Jeffrey H. Sen, Sabyasachi |
| description | A fundamental mechanistic understanding of the pressure- and/or temperature-induced facile transformation of the coordination environment of boron is important for changing the physical properties of glass. We have used in situ high-pressure (up to 2 gigapascals) boron-11 solid-state nuclear magnetic resonance spectroscopy in combination with ab initio calculations to investigate the nature of the transition state for the pressure-induced BO₃→ BO₄ conversion in a borosilicate glass at ambient temperature. The results indicate an anisotropic elastic deformation of the BO₃ planar triangle, under isotropic stress, into a trigonal pyramid that likely serves as a precursor for the subsequent formation of a BO₄ tetrahedron. |
| doi_str_mv | 10.1126/science.1256224 |
| format | Article |
| fullrecord | <record><control><sourceid>jstor_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_1558524132</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><jstor_id>24917323</jstor_id><sourcerecordid>24917323</sourcerecordid><originalsourceid>FETCH-LOGICAL-j191t-639646531332a80486414cc0546fe1bc5684208d8fab52071cb1d3c309dc550a3</originalsourceid><addsrcrecordid>eNpdkEtLw0AUhQdRbK2uXSkBN25S586ryVKLLyh0oxs3YTKZaEI6U2cmBbcq_gB_Yn-J6UMEVwfu-e65h4vQMeAhABEXXlXaKD0EwgUhbAf1Aac8Tgmmu6iPMRVxgke8hw68rzHuvJTuox7hMMLARB89TXOv3UKGyprIllF40VFw0vhqPfFBBh2V1kVzp71vnY4rU7RKF9HVdPn-sfz6XulnpKxZaOdXO5WJnhvp_SHaK2Xj9dFWB-jx5vphfBdPprf348tJXEMKIRY0FUxwCpQSmWCWCAZMKcyZKDXkiouEEZwUSSlzTvAIVA4FVRSnheIcSzpA55vcubOvrfYhm1Ve6aaRRtvWZ8B5wgkDSjr07B9a29aZrt2a6sI5Fh11uqXafKaLbO6qmXRv2e_XOuBkA9Q-WPfnsxRG3RX6A9peegA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1558071506</pqid></control><display><type>article</type><title>Observation of the transition state for pressure-induced BO₃→BO₄ conversion in glass</title><source>Science Magazine</source><source>JSTOR Archive Collection A-Z Listing</source><creator>Edwards, Trenton ; Endo, Takatsugu ; Walton, Jeffrey H. ; Sen, Sabyasachi</creator><creatorcontrib>Edwards, Trenton ; Endo, Takatsugu ; Walton, Jeffrey H. ; Sen, Sabyasachi</creatorcontrib><description>A fundamental mechanistic understanding of the pressure- and/or temperature-induced facile transformation of the coordination environment of boron is important for changing the physical properties of glass. We have used in situ high-pressure (up to 2 gigapascals) boron-11 solid-state nuclear magnetic resonance spectroscopy in combination with ab initio calculations to investigate the nature of the transition state for the pressure-induced BO₃→ BO₄ conversion in a borosilicate glass at ambient temperature. The results indicate an anisotropic elastic deformation of the BO₃ planar triangle, under isotropic stress, into a trigonal pyramid that likely serves as a precursor for the subsequent formation of a BO₄ tetrahedron.</description><identifier>ISSN: 0036-8075</identifier><identifier>EISSN: 1095-9203</identifier><identifier>DOI: 10.1126/science.1256224</identifier><identifier>PMID: 25170146</identifier><identifier>CODEN: SCIEAS</identifier><language>eng</language><publisher>United States: American Association for the Advancement of Science</publisher><subject>Crystal structure ; Glass ; Materials science ; NMR ; Nuclear magnetic resonance ; Pressure</subject><ispartof>Science (American Association for the Advancement of Science), 2014-08, Vol.345 (6200), p.1027-1029</ispartof><rights>Copyright © 2014 American Association for the Advancement of Science</rights><rights>Copyright © 2014, American Association for the Advancement of Science.</rights><rights>Copyright © 2014, American Association for the Advancement of Science</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/24917323$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/24917323$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>315,781,785,804,27929,27930,58022,58255</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25170146$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Edwards, Trenton</creatorcontrib><creatorcontrib>Endo, Takatsugu</creatorcontrib><creatorcontrib>Walton, Jeffrey H.</creatorcontrib><creatorcontrib>Sen, Sabyasachi</creatorcontrib><title>Observation of the transition state for pressure-induced BO₃→BO₄ conversion in glass</title><title>Science (American Association for the Advancement of Science)</title><addtitle>Science</addtitle><description>A fundamental mechanistic understanding of the pressure- and/or temperature-induced facile transformation of the coordination environment of boron is important for changing the physical properties of glass. We have used in situ high-pressure (up to 2 gigapascals) boron-11 solid-state nuclear magnetic resonance spectroscopy in combination with ab initio calculations to investigate the nature of the transition state for the pressure-induced BO₃→ BO₄ conversion in a borosilicate glass at ambient temperature. The results indicate an anisotropic elastic deformation of the BO₃ planar triangle, under isotropic stress, into a trigonal pyramid that likely serves as a precursor for the subsequent formation of a BO₄ tetrahedron.</description><subject>Crystal structure</subject><subject>Glass</subject><subject>Materials science</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Pressure</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpdkEtLw0AUhQdRbK2uXSkBN25S586ryVKLLyh0oxs3YTKZaEI6U2cmBbcq_gB_Yn-J6UMEVwfu-e65h4vQMeAhABEXXlXaKD0EwgUhbAf1Aac8Tgmmu6iPMRVxgke8hw68rzHuvJTuox7hMMLARB89TXOv3UKGyprIllF40VFw0vhqPfFBBh2V1kVzp71vnY4rU7RKF9HVdPn-sfz6XulnpKxZaOdXO5WJnhvp_SHaK2Xj9dFWB-jx5vphfBdPprf348tJXEMKIRY0FUxwCpQSmWCWCAZMKcyZKDXkiouEEZwUSSlzTvAIVA4FVRSnheIcSzpA55vcubOvrfYhm1Ve6aaRRtvWZ8B5wgkDSjr07B9a29aZrt2a6sI5Fh11uqXafKaLbO6qmXRv2e_XOuBkA9Q-WPfnsxRG3RX6A9peegA</recordid><startdate>20140829</startdate><enddate>20140829</enddate><creator>Edwards, Trenton</creator><creator>Endo, Takatsugu</creator><creator>Walton, Jeffrey H.</creator><creator>Sen, Sabyasachi</creator><general>American Association for the Advancement of Science</general><general>The American Association for the Advancement of Science</general><scope>NPM</scope><scope>7QF</scope><scope>7QG</scope><scope>7QL</scope><scope>7QP</scope><scope>7QQ</scope><scope>7QR</scope><scope>7SC</scope><scope>7SE</scope><scope>7SN</scope><scope>7SP</scope><scope>7SR</scope><scope>7SS</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7TK</scope><scope>7TM</scope><scope>7U5</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>K9.</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>M7N</scope><scope>P64</scope><scope>RC3</scope><scope>7X8</scope></search><sort><creationdate>20140829</creationdate><title>Observation of the transition state for pressure-induced BO₃→BO₄ conversion in glass</title><author>Edwards, Trenton ; Endo, Takatsugu ; Walton, Jeffrey H. ; Sen, Sabyasachi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j191t-639646531332a80486414cc0546fe1bc5684208d8fab52071cb1d3c309dc550a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Crystal structure</topic><topic>Glass</topic><topic>Materials science</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Pressure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Edwards, Trenton</creatorcontrib><creatorcontrib>Endo, Takatsugu</creatorcontrib><creatorcontrib>Walton, Jeffrey H.</creatorcontrib><creatorcontrib>Sen, Sabyasachi</creatorcontrib><collection>PubMed</collection><collection>Aluminium Industry Abstracts</collection><collection>Animal Behavior Abstracts</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Calcium & Calcified Tissue Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Chemoreception Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Ecology Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Entomology Abstracts (Full archive)</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Genetics Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Science (American Association for the Advancement of Science)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Edwards, Trenton</au><au>Endo, Takatsugu</au><au>Walton, Jeffrey H.</au><au>Sen, Sabyasachi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Observation of the transition state for pressure-induced BO₃→BO₄ conversion in glass</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>2014-08-29</date><risdate>2014</risdate><volume>345</volume><issue>6200</issue><spage>1027</spage><epage>1029</epage><pages>1027-1029</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><coden>SCIEAS</coden><abstract>A fundamental mechanistic understanding of the pressure- and/or temperature-induced facile transformation of the coordination environment of boron is important for changing the physical properties of glass. We have used in situ high-pressure (up to 2 gigapascals) boron-11 solid-state nuclear magnetic resonance spectroscopy in combination with ab initio calculations to investigate the nature of the transition state for the pressure-induced BO₃→ BO₄ conversion in a borosilicate glass at ambient temperature. The results indicate an anisotropic elastic deformation of the BO₃ planar triangle, under isotropic stress, into a trigonal pyramid that likely serves as a precursor for the subsequent formation of a BO₄ tetrahedron.</abstract><cop>United States</cop><pub>American Association for the Advancement of Science</pub><pmid>25170146</pmid><doi>10.1126/science.1256224</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-8075 |
| ispartof | Science (American Association for the Advancement of Science), 2014-08, Vol.345 (6200), p.1027-1029 |
| issn | 0036-8075 1095-9203 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1558524132 |
| source | Science Magazine; JSTOR Archive Collection A-Z Listing |
| subjects | Crystal structure Glass Materials science NMR Nuclear magnetic resonance Pressure |
| title | Observation of the transition state for pressure-induced BO₃→BO₄ conversion in glass |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-14T11%3A51%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-jstor_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Observation%20of%20the%20transition%20state%20for%20pressure-induced%20BO%E2%82%83%E2%86%92BO%E2%82%84%20conversion%20in%20glass&rft.jtitle=Science%20(American%20Association%20for%20the%20Advancement%20of%20Science)&rft.au=Edwards,%20Trenton&rft.date=2014-08-29&rft.volume=345&rft.issue=6200&rft.spage=1027&rft.epage=1029&rft.pages=1027-1029&rft.issn=0036-8075&rft.eissn=1095-9203&rft.coden=SCIEAS&rft_id=info:doi/10.1126/science.1256224&rft_dat=%3Cjstor_proqu%3E24917323%3C/jstor_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1558071506&rft_id=info:pmid/25170146&rft_jstor_id=24917323&rfr_iscdi=true |