Study of a magnetic-cooling material Gd(OH)CO sub(3)
The magnetocaloric effect of a coordination polymeric material with a repeating unit of Gd(OH)CO sub(3) has been studied experimentally using isothermal magnetization and heat capacity measurements. The maximum entropy change, - Delta S sub(m), reaches 66.4 J kg super(-1) K super(-1) or 355 mJ cm su...
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Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2014-06, Vol.2 (25), p.9851-9858 |
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creator | Chen, Yan-Cong Qin, Lei Meng, Zhao-Sha Yang, Ding-Feng Wu, Chao Fu, Zhendong Zheng, Yan-Zhen Liu, Jun-Liang Tarasenko, Robert Orendac, Martin Prokleska, Jan Sechovsky, Vladimir Tong, Ming-Liang |
description | The magnetocaloric effect of a coordination polymeric material with a repeating unit of Gd(OH)CO sub(3) has been studied experimentally using isothermal magnetization and heat capacity measurements. The maximum entropy change, - Delta S sub(m), reaches 66.4 J kg super(-1) K super(-1) or 355 mJ cm super(-3) K super(-1) for Delta H= 7 T and T= 1.8 K. Density functional theory (DFT) calculations show weak and competing antiferromagnetic interactions between the metal centres. |
doi_str_mv | 10.1039/c4ta01646g |
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title | Study of a magnetic-cooling material Gd(OH)CO sub(3) |
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