NO-binding in {Ru(NO)₂}⁸-type [Ru(NO)₂(PR₃)₂X]BF₄ compounds

Two different structure types were found for a series of mononuclear dinitrosyl complexes of the general formula [RuL2(NO)2X]BF4 (L = monodentate phosphane, X = Cl, Br, I). The {Ru(NO)2}(8)-type target compounds were prepared by the reduction of the respective {RuNO}(6) precursors and subsequent oxi...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-09, Vol.43 (35), p.13278-13292
Hauptverfasser:	Gallien, Anna K E, Schaniel, Dominik, Woike, Theo, Klüfers, Peter
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding Sites Borates - chemistry Borates - metabolism Crystallization Nitric Oxide - chemistry Nitric Oxide - metabolism Organophosphorus Compounds - chemistry Ruthenium - chemistry Ruthenium - metabolism Spectrophotometry, Infrared - methods
Online-Zugang:	Volltext
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