Synthesis, characterization and photoelectrochemical properties of polyindole-CdTe hybrid material

Polyindole-CdTe (PIN-CdTe) films were prepared by electropolymerization of indole on Pt electrode followed by electrodeposition of CdTe. The synthesized composites were characterized by Raman spectra, UV-vis absorption spectra and SEM images. Photoresponses and photostability of Pt/PIN-CdTe electrod...

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Veröffentlicht in:Electrochimica acta 2014-03, Vol.122, p.275-281
Hauptverfasser: Osial, Magdalena, Widera, Justyna, Jackowska, Krystyna
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description Polyindole-CdTe (PIN-CdTe) films were prepared by electropolymerization of indole on Pt electrode followed by electrodeposition of CdTe. The synthesized composites were characterized by Raman spectra, UV-vis absorption spectra and SEM images. Photoresponses and photostability of Pt/PIN-CdTe electrodes were determined in polysulphide solution and compared with results obtained for CdTe electrodes without polymer. It was found, that the photocurrent for Pt/PIN-CdTe electrodes is nearly two fold higher and more stable than for Pt/CdTe electrodes. Raman spectra recorded after photo measurements in polysulphides revealed CdS formation. Energy dispersive X-ray spectra (EDS) indicated that amount of CdS formed was higher for CdTe deposits without polymer.
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subjects Cadmium sulfides
Cadmium tellurides
CdS formation
CdTe
CdTe-PIN hybrid electrode
Electrodes
Photocurrent
Photoelectric effect
Photostability in polysulphide
Platinum
Polyindole
Polysulphides
Raman spectra
title Synthesis, characterization and photoelectrochemical properties of polyindole-CdTe hybrid material
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