Production of SBA-15 mesoporous silica containing ammonium groups in the surface layer
The template method (surfactant: Pluronic 123) has been applied to produce mesoporous silica that contain ammonium groups [≡Si(CH 2 ) 3 NH 3 ] + , [≡Si(CH 2 ) 3 NH 2 (CH 2 ) 2 NH 3 ] 2+ , [≡Si(CH 2 ) 3 NH 2 (CH 2 ) 2 NH 2 (CH 2 ) 2 NH 3 ] 3+ and [≡Si(CH 2 ) 3 N(CH 3 ) 3 ] + in the surface layer, whi...
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| Veröffentlicht in: | Protection of metals and physical chemistry of surfaces 2014-05, Vol.50 (3), p.293-299 |
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| container_title | Protection of metals and physical chemistry of surfaces |
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| creator | Slesarenko, V. V. Dudarko, O. A. Shcherbatyuk, N. N. Zub, Yu. L. |
| description | The template method (surfactant: Pluronic 123) has been applied to produce mesoporous silica that contain ammonium groups [≡Si(CH
2
)
3
NH
3
]
+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
3
]
2+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
2
(CH
2
)
2
NH
3
]
3+
and [≡Si(CH
2
)
3
N(CH
3
)
3
]
+
in the surface layer, which has been confirmed both by data of elemental analysis for nitrogen and by IR spectroscopy. Using diffractometry and TEM, it has been demonstrated that the synthesized samples contain a hexagonal structure characteristic of SBA-15 silica. This agrees with the parameters of their porous structure calculated by isotherms of low-temperature adsorption of nitrogen:
S
sp
= 520–750 m
2
/g,
V
c
= 0.6–1.2 cm
3
/g, and
d
= 4.9–8.9 nm. |
| doi_str_mv | 10.1134/S2070205114030216 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1551093990</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1551093990</sourcerecordid><originalsourceid>FETCH-LOGICAL-c386t-6b814ba97a28f5383adc68b8cc1abd501ce92f99ba03913bbaa2c079ed189b293</originalsourceid><addsrcrecordid>eNp1kEtLxDAUhYsoOD5-gLuAGzfV3KRpk-U4-IIBhVFxV5I0HTO0yZi0i_n3ZhgRUVzdw-U7h8PJsjPAlwC0uFoQXGGCGUCBKSZQ7mWT7SsnuHzb_9YMDrOjGFcYl2XFq0n2-hR8M-rBeod8ixbX0xwY6k30ax_8GFG0ndUSae8GaZ11SyT73js79miZgHVE1qHh3aA4hlZqgzq5MeEkO2hlF83p1z3OXm5vnmf3-fzx7mE2neea8nLIS8WhUFJUkvCWUU5lo0uuuNYgVcMwaCNIK4SSmAqgSklJNK6EaYALRQQ9zi52uevgP0YTh7q3UZuuk86k9jUwBlhQIXBCz3-hKz8Gl9olijBSQFotUbCjdPAxBtPW62B7GTY14Hq7dP1n6eQhO09MrFua8CP5X9MnwMN_DQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1525241216</pqid></control><display><type>article</type><title>Production of SBA-15 mesoporous silica containing ammonium groups in the surface layer</title><source>SpringerNature Journals</source><creator>Slesarenko, V. V. ; Dudarko, O. A. ; Shcherbatyuk, N. N. ; Zub, Yu. L.</creator><creatorcontrib>Slesarenko, V. V. ; Dudarko, O. A. ; Shcherbatyuk, N. N. ; Zub, Yu. L.</creatorcontrib><description>The template method (surfactant: Pluronic 123) has been applied to produce mesoporous silica that contain ammonium groups [≡Si(CH
2
)
3
NH
3
]
+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
3
]
2+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
2
(CH
2
)
2
NH
3
]
3+
and [≡Si(CH
2
)
3
N(CH
3
)
3
]
+
in the surface layer, which has been confirmed both by data of elemental analysis for nitrogen and by IR spectroscopy. Using diffractometry and TEM, it has been demonstrated that the synthesized samples contain a hexagonal structure characteristic of SBA-15 silica. This agrees with the parameters of their porous structure calculated by isotherms of low-temperature adsorption of nitrogen:
S
sp
= 520–750 m
2
/g,
V
c
= 0.6–1.2 cm
3
/g, and
d
= 4.9–8.9 nm.</description><identifier>ISSN: 2070-2051</identifier><identifier>EISSN: 2070-206X</identifier><identifier>DOI: 10.1134/S2070205114030216</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Corrosion and Coatings ; Diffraction ; Industrial Chemistry/Chemical Engineering ; Infrared radiation ; Inorganic Chemistry ; Isotherms ; Materials Science ; Mathematical analysis ; Metallic Materials ; Physicochemical Processes at the Interfaces ; Silicon dioxide ; Surface chemistry ; Surface layer ; Transmission electron microscopy ; Tribology</subject><ispartof>Protection of metals and physical chemistry of surfaces, 2014-05, Vol.50 (3), p.293-299</ispartof><rights>Pleiades Publishing, Ltd. 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-6b814ba97a28f5383adc68b8cc1abd501ce92f99ba03913bbaa2c079ed189b293</citedby><cites>FETCH-LOGICAL-c386t-6b814ba97a28f5383adc68b8cc1abd501ce92f99ba03913bbaa2c079ed189b293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S2070205114030216$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S2070205114030216$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Slesarenko, V. V.</creatorcontrib><creatorcontrib>Dudarko, O. A.</creatorcontrib><creatorcontrib>Shcherbatyuk, N. N.</creatorcontrib><creatorcontrib>Zub, Yu. L.</creatorcontrib><title>Production of SBA-15 mesoporous silica containing ammonium groups in the surface layer</title><title>Protection of metals and physical chemistry of surfaces</title><addtitle>Prot Met Phys Chem Surf</addtitle><description>The template method (surfactant: Pluronic 123) has been applied to produce mesoporous silica that contain ammonium groups [≡Si(CH
2
)
3
NH
3
]
+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
3
]
2+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
2
(CH
2
)
2
NH
3
]
3+
and [≡Si(CH
2
)
3
N(CH
3
)
3
]
+
in the surface layer, which has been confirmed both by data of elemental analysis for nitrogen and by IR spectroscopy. Using diffractometry and TEM, it has been demonstrated that the synthesized samples contain a hexagonal structure characteristic of SBA-15 silica. This agrees with the parameters of their porous structure calculated by isotherms of low-temperature adsorption of nitrogen:
S
sp
= 520–750 m
2
/g,
V
c
= 0.6–1.2 cm
3
/g, and
d
= 4.9–8.9 nm.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion and Coatings</subject><subject>Diffraction</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared radiation</subject><subject>Inorganic Chemistry</subject><subject>Isotherms</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Metallic Materials</subject><subject>Physicochemical Processes at the Interfaces</subject><subject>Silicon dioxide</subject><subject>Surface chemistry</subject><subject>Surface layer</subject><subject>Transmission electron microscopy</subject><subject>Tribology</subject><issn>2070-2051</issn><issn>2070-206X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLxDAUhYsoOD5-gLuAGzfV3KRpk-U4-IIBhVFxV5I0HTO0yZi0i_n3ZhgRUVzdw-U7h8PJsjPAlwC0uFoQXGGCGUCBKSZQ7mWT7SsnuHzb_9YMDrOjGFcYl2XFq0n2-hR8M-rBeod8ixbX0xwY6k30ax_8GFG0ndUSae8GaZ11SyT73js79miZgHVE1qHh3aA4hlZqgzq5MeEkO2hlF83p1z3OXm5vnmf3-fzx7mE2neea8nLIS8WhUFJUkvCWUU5lo0uuuNYgVcMwaCNIK4SSmAqgSklJNK6EaYALRQQ9zi52uevgP0YTh7q3UZuuk86k9jUwBlhQIXBCz3-hKz8Gl9olijBSQFotUbCjdPAxBtPW62B7GTY14Hq7dP1n6eQhO09MrFua8CP5X9MnwMN_DQ</recordid><startdate>20140501</startdate><enddate>20140501</enddate><creator>Slesarenko, V. V.</creator><creator>Dudarko, O. A.</creator><creator>Shcherbatyuk, N. N.</creator><creator>Zub, Yu. L.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>20140501</creationdate><title>Production of SBA-15 mesoporous silica containing ammonium groups in the surface layer</title><author>Slesarenko, V. V. ; Dudarko, O. A. ; Shcherbatyuk, N. N. ; Zub, Yu. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-6b814ba97a28f5383adc68b8cc1abd501ce92f99ba03913bbaa2c079ed189b293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion and Coatings</topic><topic>Diffraction</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared radiation</topic><topic>Inorganic Chemistry</topic><topic>Isotherms</topic><topic>Materials Science</topic><topic>Mathematical analysis</topic><topic>Metallic Materials</topic><topic>Physicochemical Processes at the Interfaces</topic><topic>Silicon dioxide</topic><topic>Surface chemistry</topic><topic>Surface layer</topic><topic>Transmission electron microscopy</topic><topic>Tribology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Slesarenko, V. V.</creatorcontrib><creatorcontrib>Dudarko, O. A.</creatorcontrib><creatorcontrib>Shcherbatyuk, N. N.</creatorcontrib><creatorcontrib>Zub, Yu. L.</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Protection of metals and physical chemistry of surfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Slesarenko, V. V.</au><au>Dudarko, O. A.</au><au>Shcherbatyuk, N. N.</au><au>Zub, Yu. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Production of SBA-15 mesoporous silica containing ammonium groups in the surface layer</atitle><jtitle>Protection of metals and physical chemistry of surfaces</jtitle><stitle>Prot Met Phys Chem Surf</stitle><date>2014-05-01</date><risdate>2014</risdate><volume>50</volume><issue>3</issue><spage>293</spage><epage>299</epage><pages>293-299</pages><issn>2070-2051</issn><eissn>2070-206X</eissn><abstract>The template method (surfactant: Pluronic 123) has been applied to produce mesoporous silica that contain ammonium groups [≡Si(CH
2
)
3
NH
3
]
+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
3
]
2+
, [≡Si(CH
2
)
3
NH
2
(CH
2
)
2
NH
2
(CH
2
)
2
NH
3
]
3+
and [≡Si(CH
2
)
3
N(CH
3
)
3
]
+
in the surface layer, which has been confirmed both by data of elemental analysis for nitrogen and by IR spectroscopy. Using diffractometry and TEM, it has been demonstrated that the synthesized samples contain a hexagonal structure characteristic of SBA-15 silica. This agrees with the parameters of their porous structure calculated by isotherms of low-temperature adsorption of nitrogen:
S
sp
= 520–750 m
2
/g,
V
c
= 0.6–1.2 cm
3
/g, and
d
= 4.9–8.9 nm.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S2070205114030216</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2070-2051 |
| ispartof | Protection of metals and physical chemistry of surfaces, 2014-05, Vol.50 (3), p.293-299 |
| issn | 2070-2051 2070-206X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1551093990 |
| source | SpringerNature Journals |
| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Corrosion and Coatings Diffraction Industrial Chemistry/Chemical Engineering Infrared radiation Inorganic Chemistry Isotherms Materials Science Mathematical analysis Metallic Materials Physicochemical Processes at the Interfaces Silicon dioxide Surface chemistry Surface layer Transmission electron microscopy Tribology |
| title | Production of SBA-15 mesoporous silica containing ammonium groups in the surface layer |
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