Evaluation of new chemically modified coconut shell adsorbents with tannic acid for Cu (II) removal from wastewater

The adsorption of Cu (II) from aqueous solutions using coconut shell modified powder was investigated in batch experiments. The surface charge of the adsorbent was determined. The points of zero charge (PZC) of the adsorbents (pH PZC ) were 4.5, 2.0, and 2.0 to raw coconut (RC), raw coconut alkalize...

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Veröffentlicht in:Journal of applied polymer science 2014-09, Vol.131 (18), p.9087-n/a
Hauptverfasser: de Oliveira Sousa Neto, Vicente, Melo, Diego Quadros, de Oliveira, Talles Cardoso, Nonato, Raimundo, Teixeira, P., Silva, Marcos Antônio Araújo, Nascimento, Ronaldo Ferreira do
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container_issue 18
container_start_page 9087
container_title Journal of applied polymer science
container_volume 131
creator de Oliveira Sousa Neto, Vicente
Melo, Diego Quadros
de Oliveira, Talles Cardoso
Nonato, Raimundo
Teixeira, P.
Silva, Marcos Antônio Araújo
Nascimento, Ronaldo Ferreira do
description The adsorption of Cu (II) from aqueous solutions using coconut shell modified powder was investigated in batch experiments. The surface charge of the adsorbent was determined. The points of zero charge (PZC) of the adsorbents (pH PZC ) were 4.5, 2.0, and 2.0 to raw coconut (RC), raw coconut alkalized (RCA), and coconut shell modified with tannic acid (TCA) adsorbent, respectively. Batch experiments were performed under kinetic and equilibrium conditions. The kinetic data were analyzed using a pseudo second‐order, and Elovich equation. Adsorption equilibrium data were investigated using the Langmiur, Freundlich, Temkin, and Dubinin–Raduschevich (D–R) isotherm models. It has been found that chemically modified coconut shell (TAC) affected performance when compared with unmodified coconut shell (RC). Kinetic studies showed that the adsorption followed a pseudo‐second‐order rate model. Biosorption kinetics of Cu(II) on the adsorbent TCA was rapid such that almost 90% of Cu(II) were adsorbed within 80 min. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40744.
doi_str_mv 10.1002/app.40744
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The surface charge of the adsorbent was determined. The points of zero charge (PZC) of the adsorbents (pH PZC ) were 4.5, 2.0, and 2.0 to raw coconut (RC), raw coconut alkalized (RCA), and coconut shell modified with tannic acid (TCA) adsorbent, respectively. Batch experiments were performed under kinetic and equilibrium conditions. The kinetic data were analyzed using a pseudo second‐order, and Elovich equation. Adsorption equilibrium data were investigated using the Langmiur, Freundlich, Temkin, and Dubinin–Raduschevich (D–R) isotherm models. It has been found that chemically modified coconut shell (TAC) affected performance when compared with unmodified coconut shell (RC). Kinetic studies showed that the adsorption followed a pseudo‐second‐order rate model. Biosorption kinetics of Cu(II) on the adsorbent TCA was rapid such that almost 90% of Cu(II) were adsorbed within 80 min. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. 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Appl. Polym. Sci</addtitle><description>The adsorption of Cu (II) from aqueous solutions using coconut shell modified powder was investigated in batch experiments. The surface charge of the adsorbent was determined. The points of zero charge (PZC) of the adsorbents (pH PZC ) were 4.5, 2.0, and 2.0 to raw coconut (RC), raw coconut alkalized (RCA), and coconut shell modified with tannic acid (TCA) adsorbent, respectively. Batch experiments were performed under kinetic and equilibrium conditions. The kinetic data were analyzed using a pseudo second‐order, and Elovich equation. Adsorption equilibrium data were investigated using the Langmiur, Freundlich, Temkin, and Dubinin–Raduschevich (D–R) isotherm models. It has been found that chemically modified coconut shell (TAC) affected performance when compared with unmodified coconut shell (RC). Kinetic studies showed that the adsorption followed a pseudo‐second‐order rate model. Biosorption kinetics of Cu(II) on the adsorbent TCA was rapid such that almost 90% of Cu(II) were adsorbed within 80 min. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40744.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Agronomy. Soil science and plant productions</subject><subject>Applied sciences</subject><subject>Aqueous solutions</subject><subject>Biological and medical sciences</subject><subject>Cellulose and derivatives</subject><subject>cellulose and other wood products</subject><subject>Copper</subject><subject>Equilibrium conditions</subject><subject>Exact sciences and technology</subject><subject>fibers</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General agronomy. Plant production</subject><subject>Glass transition temperature</subject><subject>kinetics</subject><subject>Materials science</subject><subject>Natural polymers</subject><subject>Papal visits</subject><subject>Physicochemistry of polymers</subject><subject>Pollution</subject><subject>Polymers</subject><subject>Raw</subject><subject>Shells</subject><subject>Surface charge</subject><subject>Surface chemistry</subject><subject>Tannic acid</subject><subject>theory and modeling</subject><subject>Use of agricultural and forest wastes. 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It has been found that chemically modified coconut shell (TAC) affected performance when compared with unmodified coconut shell (RC). Kinetic studies showed that the adsorption followed a pseudo‐second‐order rate model. Biosorption kinetics of Cu(II) on the adsorbent TCA was rapid such that almost 90% of Cu(II) were adsorbed within 80 min. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40744.</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.40744</doi><tpages>11</tpages></addata></record>
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subjects Adsorbents
Adsorption
Agronomy. Soil science and plant productions
Applied sciences
Aqueous solutions
Biological and medical sciences
Cellulose and derivatives
cellulose and other wood products
Copper
Equilibrium conditions
Exact sciences and technology
fibers
Fundamental and applied biological sciences. Psychology
General agronomy. Plant production
Glass transition temperature
kinetics
Materials science
Natural polymers
Papal visits
Physicochemistry of polymers
Pollution
Polymers
Raw
Shells
Surface charge
Surface chemistry
Tannic acid
theory and modeling
Use of agricultural and forest wastes. Biomass use, bioconversion
Wastewater treatment
Wastewaters
Water treatment and pollution
title Evaluation of new chemically modified coconut shell adsorbents with tannic acid for Cu (II) removal from wastewater
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