Synthesis of hydrogels by polymerization of itaconic acid-choline chloride deep eutectic solvent
ABSTRACT Itaconic acid (IA)–choline chloride (CC) deep eutectic solvents (DES) were prepared and characterized by NMR, TGA, and DSC. Poly(itaconic acid–co–bisacrylamide) hydrogels were synthesized by in situ polymerization‐crosslinking of the DES. For comparison, the hydrogels were also prepared in...
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| creator | Bednarz, Szczepan Fluder, Maria Galica, Mateusz Bogdal, Dariusz Maciejaszek, Ireneusz |
| description | ABSTRACT
Itaconic acid (IA)–choline chloride (CC) deep eutectic solvents (DES) were prepared and characterized by NMR, TGA, and DSC. Poly(itaconic acid–co–bisacrylamide) hydrogels were synthesized by in situ polymerization‐crosslinking of the DES. For comparison, the hydrogels were also prepared in water under the same process conditions, that is, temperature, time, initial concentration of the monomer, the initiator, and N,N′‐methylenebisacrylamide (BAA) as the cross‐linking agent. Chemical structure of the polymers was proved by elemental analysis and FTIR. The values of insoluble gel fraction and water swelling of obtained hydrogels suggest that polymers prepared in DES have higher cross‐link density. Preliminary comparative studies of polymerization of IA in water and in DES medium indicated higher polymerization rate resulting from the presence of the choline salt, what might explain properties of the hydrogels prepared in DES. This study shows that DES can be used both as a solvent and catalyst in free‐radical polymerization processes. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40608. |
| doi_str_mv | 10.1002/app.40608 |
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Itaconic acid (IA)–choline chloride (CC) deep eutectic solvents (DES) were prepared and characterized by NMR, TGA, and DSC. Poly(itaconic acid–co–bisacrylamide) hydrogels were synthesized by in situ polymerization‐crosslinking of the DES. For comparison, the hydrogels were also prepared in water under the same process conditions, that is, temperature, time, initial concentration of the monomer, the initiator, and N,N′‐methylenebisacrylamide (BAA) as the cross‐linking agent. Chemical structure of the polymers was proved by elemental analysis and FTIR. The values of insoluble gel fraction and water swelling of obtained hydrogels suggest that polymers prepared in DES have higher cross‐link density. Preliminary comparative studies of polymerization of IA in water and in DES medium indicated higher polymerization rate resulting from the presence of the choline salt, what might explain properties of the hydrogels prepared in DES. This study shows that DES can be used both as a solvent and catalyst in free‐radical polymerization processes. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40608.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.40608</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken, NJ: Blackwell Publishing Ltd</publisher><subject>Applied sciences ; Chlorides ; copolymers ; Crosslinking ; Density ; Differential scanning calorimetry ; Exact sciences and technology ; gels ; Hydrogels ; ionic liquids ; Materials science ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Polymers ; Properties and characterization ; radical polymerization ; Solution and gel properties ; Solvents ; Swelling</subject><ispartof>Journal of applied polymer science, 2014-08, Vol.131 (16), p.np-n/a</ispartof><rights>Copyright © 2014 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3988-f9577727ef89811fbad4fe375a626f41b166bbc79c136c87a0d0c3de10fe01b93</citedby><cites>FETCH-LOGICAL-c3988-f9577727ef89811fbad4fe375a626f41b166bbc79c136c87a0d0c3de10fe01b93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.40608$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.40608$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28505915$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Bednarz, Szczepan</creatorcontrib><creatorcontrib>Fluder, Maria</creatorcontrib><creatorcontrib>Galica, Mateusz</creatorcontrib><creatorcontrib>Bogdal, Dariusz</creatorcontrib><creatorcontrib>Maciejaszek, Ireneusz</creatorcontrib><title>Synthesis of hydrogels by polymerization of itaconic acid-choline chloride deep eutectic solvent</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>ABSTRACT
Itaconic acid (IA)–choline chloride (CC) deep eutectic solvents (DES) were prepared and characterized by NMR, TGA, and DSC. Poly(itaconic acid–co–bisacrylamide) hydrogels were synthesized by in situ polymerization‐crosslinking of the DES. For comparison, the hydrogels were also prepared in water under the same process conditions, that is, temperature, time, initial concentration of the monomer, the initiator, and N,N′‐methylenebisacrylamide (BAA) as the cross‐linking agent. Chemical structure of the polymers was proved by elemental analysis and FTIR. The values of insoluble gel fraction and water swelling of obtained hydrogels suggest that polymers prepared in DES have higher cross‐link density. Preliminary comparative studies of polymerization of IA in water and in DES medium indicated higher polymerization rate resulting from the presence of the choline salt, what might explain properties of the hydrogels prepared in DES. This study shows that DES can be used both as a solvent and catalyst in free‐radical polymerization processes. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40608.</description><subject>Applied sciences</subject><subject>Chlorides</subject><subject>copolymers</subject><subject>Crosslinking</subject><subject>Density</subject><subject>Differential scanning calorimetry</subject><subject>Exact sciences and technology</subject><subject>gels</subject><subject>Hydrogels</subject><subject>ionic liquids</subject><subject>Materials science</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Properties and characterization</subject><subject>radical polymerization</subject><subject>Solution and gel properties</subject><subject>Solvents</subject><subject>Swelling</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp1kE1v1DAQhq0KpC6FQ_9BJIQEh7S2E38dqwoWUKErAe3RdZwx6-KNg50Fwq_Hy5YekHqawzzvO6MHoWOCTwjG9NSM40mLOZYHaEGwEnXLqXyEFmVHaqkUO0RPcr7FmBCG-QLdfJqHaQ3Z5yq6aj33KX6FkKtursYY5g0k_9tMPg67tZ-MjYO3lbG-r-06Bj9AZdchJt9D1QOMFWwnsFNhcgw_YJieosfOhAzP7uYR-vLm9efzt_XF5fLd-dlFbRslZe0UE0JQAU4qSYjrTN86aAQznHLXko5w3nVWKEsabqUwuMe26YFgB5h0qjlCL_e9Y4rft5AnvfHZQghmgLjNmjBGcMsUZQV9_h96G7dpKN8VijKFG0ploV7tKZtizgmcHpPfmDRrgvXOtS6u9V_XhX1x12iyNcElM1if7wNUMswU2V0-3XM_fYD54UJ9tlr9a673CZ8n-HWfMOmb5qLo0dcfl3rJ3kt69UHoVfMH8zuczQ</recordid><startdate>20140815</startdate><enddate>20140815</enddate><creator>Bednarz, Szczepan</creator><creator>Fluder, Maria</creator><creator>Galica, Mateusz</creator><creator>Bogdal, Dariusz</creator><creator>Maciejaszek, Ireneusz</creator><general>Blackwell Publishing Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>20140815</creationdate><title>Synthesis of hydrogels by polymerization of itaconic acid-choline chloride deep eutectic solvent</title><author>Bednarz, Szczepan ; Fluder, Maria ; Galica, Mateusz ; Bogdal, Dariusz ; Maciejaszek, Ireneusz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3988-f9577727ef89811fbad4fe375a626f41b166bbc79c136c87a0d0c3de10fe01b93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Chlorides</topic><topic>copolymers</topic><topic>Crosslinking</topic><topic>Density</topic><topic>Differential scanning calorimetry</topic><topic>Exact sciences and technology</topic><topic>gels</topic><topic>Hydrogels</topic><topic>ionic liquids</topic><topic>Materials science</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Properties and characterization</topic><topic>radical polymerization</topic><topic>Solution and gel properties</topic><topic>Solvents</topic><topic>Swelling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bednarz, Szczepan</creatorcontrib><creatorcontrib>Fluder, Maria</creatorcontrib><creatorcontrib>Galica, Mateusz</creatorcontrib><creatorcontrib>Bogdal, Dariusz</creatorcontrib><creatorcontrib>Maciejaszek, Ireneusz</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bednarz, Szczepan</au><au>Fluder, Maria</au><au>Galica, Mateusz</au><au>Bogdal, Dariusz</au><au>Maciejaszek, Ireneusz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of hydrogels by polymerization of itaconic acid-choline chloride deep eutectic solvent</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2014-08-15</date><risdate>2014</risdate><volume>131</volume><issue>16</issue><spage>np</spage><epage>n/a</epage><pages>np-n/a</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>ABSTRACT
Itaconic acid (IA)–choline chloride (CC) deep eutectic solvents (DES) were prepared and characterized by NMR, TGA, and DSC. Poly(itaconic acid–co–bisacrylamide) hydrogels were synthesized by in situ polymerization‐crosslinking of the DES. For comparison, the hydrogels were also prepared in water under the same process conditions, that is, temperature, time, initial concentration of the monomer, the initiator, and N,N′‐methylenebisacrylamide (BAA) as the cross‐linking agent. Chemical structure of the polymers was proved by elemental analysis and FTIR. The values of insoluble gel fraction and water swelling of obtained hydrogels suggest that polymers prepared in DES have higher cross‐link density. Preliminary comparative studies of polymerization of IA in water and in DES medium indicated higher polymerization rate resulting from the presence of the choline salt, what might explain properties of the hydrogels prepared in DES. This study shows that DES can be used both as a solvent and catalyst in free‐radical polymerization processes. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 40608.</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/app.40608</doi><tpages>8</tpages></addata></record> |
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| subjects | Applied sciences Chlorides copolymers Crosslinking Density Differential scanning calorimetry Exact sciences and technology gels Hydrogels ionic liquids Materials science Organic polymers Physicochemistry of polymers Polymerization Polymers Properties and characterization radical polymerization Solution and gel properties Solvents Swelling |
| title | Synthesis of hydrogels by polymerization of itaconic acid-choline chloride deep eutectic solvent |
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