Stereospecific ligands and their complexes. XX. Synthesis, characterization and antimicrobial activity of palladium(II) complexes with some alkyl esters of ethylenediamine-N,N′-di-S,S-(2,2′-dibenzyl)acetic acid

The complexes have been obtained by direct reaction of potassium-tetrachloridopalladate(II) with corresponding esters of ethylenediamine-N,N′-di-S,S-(2,2′-dibenzyl)-acetic acid. [Display omitted] •Four new palladium(II) complexes were synthesized.•Characterized by microanalysis, infrared, 1H and 13C...

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Veröffentlicht in:Journal of molecular structure 2014-08, Vol.1071, p.128-132
Hauptverfasser: Dimitrijevic, Dejana P, Radic, Gordana P, Jevtic, Verica V, Misic, Milena, Baskic, Dejan, Trifunovic, Srecko R
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container_end_page 132
container_issue
container_start_page 128
container_title Journal of molecular structure
container_volume 1071
creator Dimitrijevic, Dejana P
Radic, Gordana P
Jevtic, Verica V
Misic, Milena
Baskic, Dejan
Trifunovic, Srecko R
description The complexes have been obtained by direct reaction of potassium-tetrachloridopalladate(II) with corresponding esters of ethylenediamine-N,N′-di-S,S-(2,2′-dibenzyl)-acetic acid. [Display omitted] •Four new palladium(II) complexes were synthesized.•Characterized by microanalysis, infrared, 1H and 13C NMR spectroscopy.•Antimicrobial activity was tested in relation to 6 species of microorganisms. Four new palladium(II) complexes of general formula [PdCl2(R2-S,S-eddba)] (R=ethyl, n-propyl, n-butyl and n-pentyl; S,S-eddba=ethylenediamine-N,N′-di-S,S-(2,2′-dibenzyl)acetate) have been synthesized and characterized by microanalysis, infrared, 1H and 13C NMR spectroscopy. In vitro antimicrobial activity for ligands L1–L4 general formula R2-S,S-eddba and complexes C1–C4 was investigated.
doi_str_mv 10.1016/j.molstruc.2014.05.008
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Four new palladium(II) complexes of general formula [PdCl2(R2-S,S-eddba)] (R=ethyl, n-propyl, n-butyl and n-pentyl; S,S-eddba=ethylenediamine-N,N′-di-S,S-(2,2′-dibenzyl)acetate) have been synthesized and characterized by microanalysis, infrared, 1H and 13C NMR spectroscopy. In vitro antimicrobial activity for ligands L1–L4 general formula R2-S,S-eddba and complexes C1–C4 was investigated.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.molstruc.2014.05.008</doi><tpages>5</tpages></addata></record>
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subjects 1H and 13C NMR spectroscopy
In vitro antimicrobial activity
Infrared spectroscopy
Palladium(II) complexes
title Stereospecific ligands and their complexes. XX. Synthesis, characterization and antimicrobial activity of palladium(II) complexes with some alkyl esters of ethylenediamine-N,N′-di-S,S-(2,2′-dibenzyl)acetic acid
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