Unprecedented second-timescale blue/green emissions and iodine-uptake-induced single-crystal-to-single-crystal transformation in Zn(II)/Cd(II) metal-organic frameworks

The long-persistent phosphorescent metal-organic framework (MOF) is a kind of highly desirable but rare material. Here, two new molecular MOF materials, {[Zn(tipa)Cl]⋅NO3⋅2 DMF}n (1) and {[Cd2(tipa)2Cl4]⋅6 DMF}n (2) (tipa = tri(4-imidazolylphenyl)amine), which have 3D twofold interpenetrated (utp) a...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2014-08, Vol.20 (32), p.10093-10098
Hauptverfasser:	Yuan, Shuai, Deng, Yong-Kai, Sun, Di
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!