Nickel-Catalyzed C–H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes

Nickel-Catalyzed C–H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes

It is reported that a nickel/phosphine catalyst allows the C–H allylation to occur effectively with the allyl site selectivity predominantly governed by steric effects. This reaction provides a facile and predictable route for the selective preparation of linear allylarenes from readily available be...

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Veröffentlicht in:Organic letters 2014-08, Vol.16 (15), p.3926-3929
Hauptverfasser: Cong, Xuefeng, Li, Yuexuan, Wei, Yu, Zeng, Xiaoming
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container_title Organic letters
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creator Cong, Xuefeng
Li, Yuexuan
Wei, Yu
Zeng, Xiaoming
description It is reported that a nickel/phosphine catalyst allows the C–H allylation to occur effectively with the allyl site selectivity predominantly governed by steric effects. This reaction provides a facile and predictable route for the selective preparation of linear allylarenes from readily available benzamides and allyl phosphates.
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title Nickel-Catalyzed C–H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes
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