Enhancement of (stereo)selectivity in dynamic kinetic resolution using a core-shell nanozeolite@enzyme as a bi-functional catalyst

Enhancement of (stereo)selectivity in dynamic kinetic resolution using a core-shell nanozeolite@enzyme as a bi-functional catalyst

A core-shell nanozeolite@enzyme bi-functional catalyst is constructed, which greatly improves selectivity and stereoselectivity of products in dynamic kinetic resolution of aromatic secondary alcohols compared with mixed catalysts, especially those involving small acyl donors.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (67), p.9501-9504
Hauptverfasser: Wang, Wanlu, Li, Xiang, Wang, Zhoujun, Tang, Yi, Zhang, Yahong
Format: Artikel
Sprache:eng
Schlagworte:
Benzyl Alcohols - chemistry
Biocatalysis
Fungal Proteins - metabolism
Kinetics
Lipase - metabolism
Nanoparticles - chemistry
Stereoisomerism
Substrate Specificity
Zeolites - chemistry
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Beschreibung
Zusammenfassung:A core-shell nanozeolite@enzyme bi-functional catalyst is constructed, which greatly improves selectivity and stereoselectivity of products in dynamic kinetic resolution of aromatic secondary alcohols compared with mixed catalysts, especially those involving small acyl donors.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc02112f