Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium HydroxoAquo Clusters
[Al x In y (μ3-OH)6(μ-OH)18(H2O)24](NO3)15 hydroxy–aquo clusters (Al x In13–x ) are synthesized through the evaporation of stoichiometrically varied solutions of Al13 and In(NO3)3 using a transmetalation reaction. Several spectroscopic techniques (1H NMR, 1H-diffusion ordered spectroscopy, dynamic...
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| Veröffentlicht in: | Inorganic chemistry 2014-07, Vol.53 (14), p.7101-7105 |
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| container_issue | 14 |
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| container_title | Inorganic chemistry |
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| creator | Kamunde-Devonish, Maisha K Jackson, Milton N Mensinger, Zachary L Zakharov, Lev N Johnson, Darren W |
| description | [Al x In y (μ3-OH)6(μ-OH)18(H2O)24](NO3)15 hydroxy–aquo clusters (Al x In13–x ) are synthesized through the evaporation of stoichiometrically varied solutions of Al13 and In(NO3)3 using a transmetalation reaction. Several spectroscopic techniques (1H NMR, 1H-diffusion ordered spectroscopy, dynamic light scattering, and Raman) are used to compare Al x In13–x to its Al13 counterpart. A thin film of aluminum indium oxide was prepared from an Al7In6 cluster ink, showing its utility as a precursor for materials. |
| doi_str_mv | 10.1021/ic403121r |
| format | Article |
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Several spectroscopic techniques (1H NMR, 1H-diffusion ordered spectroscopy, dynamic light scattering, and Raman) are used to compare Al x In13–x to its Al13 counterpart. A thin film of aluminum indium oxide was prepared from an Al7In6 cluster ink, showing its utility as a precursor for materials.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic403121r</identifier><identifier>PMID: 24742048</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2014-07, Vol.53 (14), p.7101-7105</ispartof><rights>Copyright © 2014 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a416t-3c15625c018963c475c7bfa68013d66217ca852215d6c43250620a6b4d6a7ea53</citedby><cites>FETCH-LOGICAL-a416t-3c15625c018963c475c7bfa68013d66217ca852215d6c43250620a6b4d6a7ea53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ic403121r$$EPDF$$P50$$Gacs$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ic403121r$$EHTML$$P50$$Gacs$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24742048$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kamunde-Devonish, Maisha K</creatorcontrib><creatorcontrib>Jackson, Milton N</creatorcontrib><creatorcontrib>Mensinger, Zachary L</creatorcontrib><creatorcontrib>Zakharov, Lev N</creatorcontrib><creatorcontrib>Johnson, Darren W</creatorcontrib><title>Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium HydroxoAquo Clusters</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>[Al x In y (μ3-OH)6(μ-OH)18(H2O)24](NO3)15 hydroxy–aquo clusters (Al x In13–x ) are synthesized through the evaporation of stoichiometrically varied solutions of Al13 and In(NO3)3 using a transmetalation reaction. Several spectroscopic techniques (1H NMR, 1H-diffusion ordered spectroscopy, dynamic light scattering, and Raman) are used to compare Al x In13–x to its Al13 counterpart. A thin film of aluminum indium oxide was prepared from an Al7In6 cluster ink, showing its utility as a precursor for materials.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>N~.</sourceid><recordid>eNptkEFKAzEUhoMotlYXXkCyEXQxmmSSTOtuKGoLBUFbcDekmYxOySQ1mYC9g3uv4qk8g6mtXbl6b_G97_H_AJxidIURwde1pCjFBLs90MWMoIRh9LwPugjFHXM-6IAj7xcIoUFK-SHoEJpRgmi_Cz6mThjfqFZo0dbWQFvB_C0oGzwcG-tehKklHOrgW-X8DczhzKsqaPhoQ6tga2H7quDTysTha78-H6mI2l-ljre5Dk1tQgOFKaOyrOM6WpXOvtvvz6_4y-70x-CgEtqrk-3sgdnd7XQ4SiYP9-NhPkkExbxNUokZJ0wi3B_wVNKMyWxeCd5HOC05JziTos8IwazkkqaEIU6Q4HNacpEpwdIeuNh4l87GrL4tmtpLpbUw6-AFZtFJeJRH9HKDSme9d6oqlq5uhFsVGBXr8otd-ZE922rDvFHljvxrOwLnG0BIXyxscCam_Ef0A_yjjVY</recordid><startdate>20140721</startdate><enddate>20140721</enddate><creator>Kamunde-Devonish, Maisha K</creator><creator>Jackson, Milton N</creator><creator>Mensinger, Zachary L</creator><creator>Zakharov, Lev N</creator><creator>Johnson, Darren W</creator><general>American Chemical Society</general><scope>N~.</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140721</creationdate><title>Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium HydroxoAquo Clusters</title><author>Kamunde-Devonish, Maisha K ; Jackson, Milton N ; Mensinger, Zachary L ; Zakharov, Lev N ; Johnson, Darren W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a416t-3c15625c018963c475c7bfa68013d66217ca852215d6c43250620a6b4d6a7ea53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kamunde-Devonish, Maisha K</creatorcontrib><creatorcontrib>Jackson, Milton N</creatorcontrib><creatorcontrib>Mensinger, Zachary L</creatorcontrib><creatorcontrib>Zakharov, Lev N</creatorcontrib><creatorcontrib>Johnson, Darren W</creatorcontrib><collection>American Chemical Society Open Access</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kamunde-Devonish, Maisha K</au><au>Jackson, Milton N</au><au>Mensinger, Zachary L</au><au>Zakharov, Lev N</au><au>Johnson, Darren W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium HydroxoAquo Clusters</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2014-07-21</date><risdate>2014</risdate><volume>53</volume><issue>14</issue><spage>7101</spage><epage>7105</epage><pages>7101-7105</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>[Al x In y (μ3-OH)6(μ-OH)18(H2O)24](NO3)15 hydroxy–aquo clusters (Al x In13–x ) are synthesized through the evaporation of stoichiometrically varied solutions of Al13 and In(NO3)3 using a transmetalation reaction. Several spectroscopic techniques (1H NMR, 1H-diffusion ordered spectroscopy, dynamic light scattering, and Raman) are used to compare Al x In13–x to its Al13 counterpart. A thin film of aluminum indium oxide was prepared from an Al7In6 cluster ink, showing its utility as a precursor for materials.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>24742048</pmid><doi>10.1021/ic403121r</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| title | Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium HydroxoAquo Clusters |
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