Biotransformation of caryophyllene by Diplodia gossypina

Fermentation of caryophyllene with Diplodia gossypina affords a number of products which are all derived from the 4,5-epoxide. Twelve of these are described here for the first time. The main products are 12-hydroxy-4,5-epoxy-caryophyllene and the corresponding acid. On side reactions additional hydr...

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Veröffentlicht in:	Phytochemistry (Oxford) 1990, Vol.29 (1), p.115-120
Hauptverfasser:	Abraham, Wolf-Rainer, Ernst, Ludger, Stumpf, Burghard
Format:	Artikel
Sprache:	eng
Schlagworte:	Bioconversions. Hemisynthesis Biological and medical sciences biosynthesis Biotechnology caryophyllene chemical structure Diplodia gossypina fermentation products filamentous fungi Fundamental and applied biological sciences. Psychology hydrolysis Methods. Procedures. Technologies microbial hydroxylation physalospora rhodina punctatin sesquiterpene terpenoids
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