A Mechanistic Change Results in 100 Times Faster CH Functionalization for Ethane versus Methane by a Homogeneous Pt Catalyst

The selective, oxidative functionalization of ethane, a significant component of shale gas, to products such as ethylene or ethanol at low temperatures and pressures remains a significant challenge. Herein we report that ethane is efficiently and selectively functionalized to the ethanol ester of H2...

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Veröffentlicht in:	J. Am. Chem Soc 2014-07, Vol.136 (28), p.10085-10094
Hauptverfasser:	Konnick, Michael M, Bischof, Steven M, Yousufuddin, Muhammed, Hashiguchi, Brian G, Ess, Daniel H, Periana, Roy A
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis (homogeneous), catalysis (heterogeneous), bio-inspired, hydrogen and fuel cells, materials and chemistry by design, synthesis (novel materials)
Online-Zugang:	Volltext
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