About the Influence of Double Bonds in the APPECVD of Acrylate-Like Precursors: A Mass Spectrometry Study of the Plasma Phase
This work deals with the in‐situ mass spectrometric (MS) characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA). By monitoring the fragments of interest, we are trying to understand the mechanisms in...
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Veröffentlicht in: | Plasma processes and polymers 2014-04, Vol.11 (4), p.335-344 |
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creator | Nisol, Bernard Arnoult, Grégory Bieber, Thomas Kakaroglou, Alexandros De Graeve, Iris Van Assche, Guy Terryn, Herman Reniers, François |
description | This work deals with the in‐situ mass spectrometric (MS) characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA). By monitoring the fragments of interest, we are trying to understand the mechanisms involved in the plasma synthesis of acrylate‐like coatings. For instance, while CO2+ drastically increases when a PiB/argon plasma is ignited, it decreases in the case of AMA. This trend also appears for other fragments, which leads to the conclusion that while PiB seems to suffer from fragmentation, AMA oligomerizes into the gas phase, resulting in a better protection of the ester functionality.
Mass spectrometry is used for the in‐situ characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA), only differing by the number of unsaturations. We highlight a different behavior of AMA which tends to oligomerize in the gas phase while PiB deposits by a fragmentation/recombination mechanism. |
doi_str_mv | 10.1002/ppap.201300176 |
format | Article |
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Mass spectrometry is used for the in‐situ characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA), only differing by the number of unsaturations. We highlight a different behavior of AMA which tends to oligomerize in the gas phase while PiB deposits by a fragmentation/recombination mechanism.</description><identifier>ISSN: 1612-8850</identifier><identifier>EISSN: 1612-8869</identifier><identifier>DOI: 10.1002/ppap.201300176</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>acrylates ; Atmospheric pressure ; Barometric pressure ; Chemical vapor deposition ; Esters ; Fragmentation ; Fragments ; Gas phases ; Mass spectrometry ; mass spectrometry (MS) ; Plasma ; plasma-enhanced chemical vapor deposition (PECVD) ; polymerization</subject><ispartof>Plasma processes and polymers, 2014-04, Vol.11 (4), p.335-344</ispartof><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4546-b42482b26b200e32ad1be61f24ac53a5289f26990ca8f88969773598eb515663</citedby><cites>FETCH-LOGICAL-c4546-b42482b26b200e32ad1be61f24ac53a5289f26990ca8f88969773598eb515663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fppap.201300176$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fppap.201300176$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Nisol, Bernard</creatorcontrib><creatorcontrib>Arnoult, Grégory</creatorcontrib><creatorcontrib>Bieber, Thomas</creatorcontrib><creatorcontrib>Kakaroglou, Alexandros</creatorcontrib><creatorcontrib>De Graeve, Iris</creatorcontrib><creatorcontrib>Van Assche, Guy</creatorcontrib><creatorcontrib>Terryn, Herman</creatorcontrib><creatorcontrib>Reniers, François</creatorcontrib><title>About the Influence of Double Bonds in the APPECVD of Acrylate-Like Precursors: A Mass Spectrometry Study of the Plasma Phase</title><title>Plasma processes and polymers</title><addtitle>Plasma Process. Polym</addtitle><description>This work deals with the in‐situ mass spectrometric (MS) characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA). By monitoring the fragments of interest, we are trying to understand the mechanisms involved in the plasma synthesis of acrylate‐like coatings. For instance, while CO2+ drastically increases when a PiB/argon plasma is ignited, it decreases in the case of AMA. This trend also appears for other fragments, which leads to the conclusion that while PiB seems to suffer from fragmentation, AMA oligomerizes into the gas phase, resulting in a better protection of the ester functionality.
Mass spectrometry is used for the in‐situ characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA), only differing by the number of unsaturations. We highlight a different behavior of AMA which tends to oligomerize in the gas phase while PiB deposits by a fragmentation/recombination mechanism.</description><subject>acrylates</subject><subject>Atmospheric pressure</subject><subject>Barometric pressure</subject><subject>Chemical vapor deposition</subject><subject>Esters</subject><subject>Fragmentation</subject><subject>Fragments</subject><subject>Gas phases</subject><subject>Mass spectrometry</subject><subject>mass spectrometry (MS)</subject><subject>Plasma</subject><subject>plasma-enhanced chemical vapor deposition (PECVD)</subject><subject>polymerization</subject><issn>1612-8850</issn><issn>1612-8869</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkc9L3EAUx0OxULW99jzQSy9Z53cmvaVRV3FrAytt6WWYzL5gNJuJMwmag_-7SbcsxUtP78H7fL48-EbRR4IXBGN60nWmW1BMGMYkkW-iQyIJjZWS6cF-F_hddBTCHcYMC4UPo-esdEOP-ltAl23VDNBaQK5Cp24oG0BfXbsJqG7_AFlRnOU_TudzZv3YmB7iVX0PqPBgBx-cD19Qhr6ZENC6A9t7t4Xej2jdD5tx1uaUojFha1BxawK8j95Wpgnw4e88jm7Oz27yi3j1fXmZZ6vYcsFlXHLKFS2pLCnGwKjZkBIkqSg3VjAjqEorKtMUW6MqpVKZJgkTqYJSECElO44-72I77x4GCL3e1sFC05gW3BA0EZxwIYUSE_rpFXrnBt9Oz03UFMYUT_hELXaU9S4ED5XufL01ftQE67kMPZeh92VMQroTHusGxv_Quiiy4l833rl16OFp7xp_r2XCEqF_Xi_1Ol8uf-VXV_o3ewE3bZsd</recordid><startdate>201404</startdate><enddate>201404</enddate><creator>Nisol, Bernard</creator><creator>Arnoult, Grégory</creator><creator>Bieber, Thomas</creator><creator>Kakaroglou, Alexandros</creator><creator>De Graeve, Iris</creator><creator>Van Assche, Guy</creator><creator>Terryn, Herman</creator><creator>Reniers, François</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201404</creationdate><title>About the Influence of Double Bonds in the APPECVD of Acrylate-Like Precursors: A Mass Spectrometry Study of the Plasma Phase</title><author>Nisol, Bernard ; Arnoult, Grégory ; Bieber, Thomas ; Kakaroglou, Alexandros ; De Graeve, Iris ; Van Assche, Guy ; Terryn, Herman ; Reniers, François</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4546-b42482b26b200e32ad1be61f24ac53a5289f26990ca8f88969773598eb515663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>acrylates</topic><topic>Atmospheric pressure</topic><topic>Barometric pressure</topic><topic>Chemical vapor deposition</topic><topic>Esters</topic><topic>Fragmentation</topic><topic>Fragments</topic><topic>Gas phases</topic><topic>Mass spectrometry</topic><topic>mass spectrometry (MS)</topic><topic>Plasma</topic><topic>plasma-enhanced chemical vapor deposition (PECVD)</topic><topic>polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nisol, Bernard</creatorcontrib><creatorcontrib>Arnoult, Grégory</creatorcontrib><creatorcontrib>Bieber, Thomas</creatorcontrib><creatorcontrib>Kakaroglou, Alexandros</creatorcontrib><creatorcontrib>De Graeve, Iris</creatorcontrib><creatorcontrib>Van Assche, Guy</creatorcontrib><creatorcontrib>Terryn, Herman</creatorcontrib><creatorcontrib>Reniers, François</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Plasma processes and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nisol, Bernard</au><au>Arnoult, Grégory</au><au>Bieber, Thomas</au><au>Kakaroglou, Alexandros</au><au>De Graeve, Iris</au><au>Van Assche, Guy</au><au>Terryn, Herman</au><au>Reniers, François</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>About the Influence of Double Bonds in the APPECVD of Acrylate-Like Precursors: A Mass Spectrometry Study of the Plasma Phase</atitle><jtitle>Plasma processes and polymers</jtitle><addtitle>Plasma Process. Polym</addtitle><date>2014-04</date><risdate>2014</risdate><volume>11</volume><issue>4</issue><spage>335</spage><epage>344</epage><pages>335-344</pages><issn>1612-8850</issn><eissn>1612-8869</eissn><abstract>This work deals with the in‐situ mass spectrometric (MS) characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA). By monitoring the fragments of interest, we are trying to understand the mechanisms involved in the plasma synthesis of acrylate‐like coatings. For instance, while CO2+ drastically increases when a PiB/argon plasma is ignited, it decreases in the case of AMA. This trend also appears for other fragments, which leads to the conclusion that while PiB seems to suffer from fragmentation, AMA oligomerizes into the gas phase, resulting in a better protection of the ester functionality.
Mass spectrometry is used for the in‐situ characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA), only differing by the number of unsaturations. We highlight a different behavior of AMA which tends to oligomerize in the gas phase while PiB deposits by a fragmentation/recombination mechanism.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/ppap.201300176</doi><tpages>10</tpages></addata></record> |
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subjects | acrylates Atmospheric pressure Barometric pressure Chemical vapor deposition Esters Fragmentation Fragments Gas phases Mass spectrometry mass spectrometry (MS) Plasma plasma-enhanced chemical vapor deposition (PECVD) polymerization |
title | About the Influence of Double Bonds in the APPECVD of Acrylate-Like Precursors: A Mass Spectrometry Study of the Plasma Phase |
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