On the Efficiency of Charge Transfer State Splitting in Polymer:Fullerene Solar Cells

The field dependence and yield of free charge carrier generation in polymer:fullerene blends with varying energetic offsets is not affected when the excitation energy is varied from above band‐gap to direct CT state excitation. Instead, the ability of the CT state to split is dictated by the energet...

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Veröffentlicht in:Advanced materials (Weinheim) 2014-04, Vol.26 (16), p.2533-2539
Hauptverfasser: Albrecht, Steve, Vandewal, Koen, Tumbleston, John R., Fischer, Florian S. U., Douglas, Jessica D., Fréchet, Jean M. J., Ludwigs, Sabine, Ade, Harald, Salleo, Alberto, Neher, Dieter
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container_end_page 2539
container_issue 16
container_start_page 2533
container_title Advanced materials (Weinheim)
container_volume 26
creator Albrecht, Steve
Vandewal, Koen
Tumbleston, John R.
Fischer, Florian S. U.
Douglas, Jessica D.
Fréchet, Jean M. J.
Ludwigs, Sabine
Ade, Harald
Salleo, Alberto
Neher, Dieter
description The field dependence and yield of free charge carrier generation in polymer:fullerene blends with varying energetic offsets is not affected when the excitation energy is varied from above band‐gap to direct CT state excitation. Instead, the ability of the CT state to split is dictated by the energetic offset between the relaxed CT state and the charge separated (CS) state.
doi_str_mv 10.1002/adma.201305283
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source Wiley Online Library Journals Frontfile Complete
subjects Charge
charge generation
Charge transfer
charge transfer states
driving force
excess energy
Excitation
geminate recombination
morphology
Offsets
organic solar cells
Photovoltaic cells
Polymer blends
Solar cells
spectroelectrochemistry
Splitting
title On the Efficiency of Charge Transfer State Splitting in Polymer:Fullerene Solar Cells
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