Diterpenes from the Endangered Goldenrod Solidago shortii
Species extinction is tantamount to loss of chemical diversity, and so it is important to seize all opportunities to study species on the brink of extinction. Such studies are often hampered by the limited material available, but that obstacle is surmountable through collaboration with botanical gar...
Gespeichert in:
| Veröffentlicht in: | Journal of natural products (Washington, D.C.) D.C.), 2014-06, Vol.77 (6), p.1438-1444 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1444 |
|---|---|
| container_issue | 6 |
| container_start_page | 1438 |
| container_title | Journal of natural products (Washington, D.C.) |
| container_volume | 77 |
| creator | Williams, Russell B Du, Lin Norman, Vanessa L Goering, Matt G O’Neil-Johnson, Mark Woodbury, Scott Albrecht, Matthew A Powell, Douglas R Cichewicz, Robert H Eldridge, Gary R Starks, Courtney M |
| description | Species extinction is tantamount to loss of chemical diversity, and so it is important to seize all opportunities to study species on the brink of extinction. Such studies are often hampered by the limited material available, but that obstacle is surmountable through collaboration with botanical gardens and advances in instrumentation. The goldenrod Solidago shortii is one example of an endangered species native to the United States. From S. shortii, one known diterpene (1), two new diterpenes (2 and 3), and three new hydrolysis products (4–6) are described. This work was made possible through collaboration with the Missouri Botanical Garden and with the use of highly sensitive microcryoprobe NMR technology for structure elucidation and VCD spectroscopy for the determination of absolute configuration. |
| doi_str_mv | 10.1021/np500178s |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1541382960</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1541382960</sourcerecordid><originalsourceid>FETCH-LOGICAL-a315t-848cadf8a1befb5c5cabf9c487540b4b472f3b18e32b56fd3ce364f09ce101ba3</originalsourceid><addsrcrecordid>eNpt0LtOw0AQheEVApEQKHgB5AYJCsPszbFLFMJFikQB1NZeZhNHttfs2gVvj1FCKqppPh1pfkIuKdxRYPS-7SQAnefxiEypZJBmwOQxmQLNeMrzTEzIWYxbAOBQyFMyYaJgLKNySorHqsfQYYsxccE3Sb_BZNla1a4xoE2efW2xDd4m776urFr7JG586KvqnJw4VUe82N8Z-Xxafixe0tXb8-viYZUqTmWf5iI3yrpcUY1OSyON0q4wIp9LAVpoMWeOa5ojZ1pmznKDPBMOCoMUqFZ8Rm52u13wXwPGvmyqaLCuVYt-iCWVgvKcFRmM9HZHTfAxBnRlF6pGhe-SQvlbqjyUGu3VfnbQDdqD_EszgusdUCaWWz-Edvzyn6EfZH9vmg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1541382960</pqid></control><display><type>article</type><title>Diterpenes from the Endangered Goldenrod Solidago shortii</title><source>MEDLINE</source><source>American Chemical Society Publications</source><creator>Williams, Russell B ; Du, Lin ; Norman, Vanessa L ; Goering, Matt G ; O’Neil-Johnson, Mark ; Woodbury, Scott ; Albrecht, Matthew A ; Powell, Douglas R ; Cichewicz, Robert H ; Eldridge, Gary R ; Starks, Courtney M</creator><creatorcontrib>Williams, Russell B ; Du, Lin ; Norman, Vanessa L ; Goering, Matt G ; O’Neil-Johnson, Mark ; Woodbury, Scott ; Albrecht, Matthew A ; Powell, Douglas R ; Cichewicz, Robert H ; Eldridge, Gary R ; Starks, Courtney M</creatorcontrib><description>Species extinction is tantamount to loss of chemical diversity, and so it is important to seize all opportunities to study species on the brink of extinction. Such studies are often hampered by the limited material available, but that obstacle is surmountable through collaboration with botanical gardens and advances in instrumentation. The goldenrod Solidago shortii is one example of an endangered species native to the United States. From S. shortii, one known diterpene (1), two new diterpenes (2 and 3), and three new hydrolysis products (4–6) are described. This work was made possible through collaboration with the Missouri Botanical Garden and with the use of highly sensitive microcryoprobe NMR technology for structure elucidation and VCD spectroscopy for the determination of absolute configuration.</description><identifier>ISSN: 0163-3864</identifier><identifier>EISSN: 1520-6025</identifier><identifier>DOI: 10.1021/np500178s</identifier><identifier>PMID: 24922615</identifier><language>eng</language><publisher>United States: American Chemical Society and American Society of Pharmacognosy</publisher><subject>Crystallography, X-Ray ; Diterpenes - chemistry ; Diterpenes - isolation & purification ; Endangered Species ; Missouri ; Molecular Conformation ; Molecular Structure ; Nuclear Magnetic Resonance, Biomolecular ; Solidago - chemistry</subject><ispartof>Journal of natural products (Washington, D.C.), 2014-06, Vol.77 (6), p.1438-1444</ispartof><rights>Copyright © 2014 American Chemical Society and American Society of Pharmacognosy</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a315t-848cadf8a1befb5c5cabf9c487540b4b472f3b18e32b56fd3ce364f09ce101ba3</citedby><cites>FETCH-LOGICAL-a315t-848cadf8a1befb5c5cabf9c487540b4b472f3b18e32b56fd3ce364f09ce101ba3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/np500178s$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/np500178s$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2756,27067,27915,27916,56729,56779</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24922615$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Williams, Russell B</creatorcontrib><creatorcontrib>Du, Lin</creatorcontrib><creatorcontrib>Norman, Vanessa L</creatorcontrib><creatorcontrib>Goering, Matt G</creatorcontrib><creatorcontrib>O’Neil-Johnson, Mark</creatorcontrib><creatorcontrib>Woodbury, Scott</creatorcontrib><creatorcontrib>Albrecht, Matthew A</creatorcontrib><creatorcontrib>Powell, Douglas R</creatorcontrib><creatorcontrib>Cichewicz, Robert H</creatorcontrib><creatorcontrib>Eldridge, Gary R</creatorcontrib><creatorcontrib>Starks, Courtney M</creatorcontrib><title>Diterpenes from the Endangered Goldenrod Solidago shortii</title><title>Journal of natural products (Washington, D.C.)</title><addtitle>J. Nat. Prod</addtitle><description>Species extinction is tantamount to loss of chemical diversity, and so it is important to seize all opportunities to study species on the brink of extinction. Such studies are often hampered by the limited material available, but that obstacle is surmountable through collaboration with botanical gardens and advances in instrumentation. The goldenrod Solidago shortii is one example of an endangered species native to the United States. From S. shortii, one known diterpene (1), two new diterpenes (2 and 3), and three new hydrolysis products (4–6) are described. This work was made possible through collaboration with the Missouri Botanical Garden and with the use of highly sensitive microcryoprobe NMR technology for structure elucidation and VCD spectroscopy for the determination of absolute configuration.</description><subject>Crystallography, X-Ray</subject><subject>Diterpenes - chemistry</subject><subject>Diterpenes - isolation & purification</subject><subject>Endangered Species</subject><subject>Missouri</subject><subject>Molecular Conformation</subject><subject>Molecular Structure</subject><subject>Nuclear Magnetic Resonance, Biomolecular</subject><subject>Solidago - chemistry</subject><issn>0163-3864</issn><issn>1520-6025</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0LtOw0AQheEVApEQKHgB5AYJCsPszbFLFMJFikQB1NZeZhNHttfs2gVvj1FCKqppPh1pfkIuKdxRYPS-7SQAnefxiEypZJBmwOQxmQLNeMrzTEzIWYxbAOBQyFMyYaJgLKNySorHqsfQYYsxccE3Sb_BZNla1a4xoE2efW2xDd4m776urFr7JG586KvqnJw4VUe82N8Z-Xxafixe0tXb8-viYZUqTmWf5iI3yrpcUY1OSyON0q4wIp9LAVpoMWeOa5ojZ1pmznKDPBMOCoMUqFZ8Rm52u13wXwPGvmyqaLCuVYt-iCWVgvKcFRmM9HZHTfAxBnRlF6pGhe-SQvlbqjyUGu3VfnbQDdqD_EszgusdUCaWWz-Edvzyn6EfZH9vmg</recordid><startdate>20140627</startdate><enddate>20140627</enddate><creator>Williams, Russell B</creator><creator>Du, Lin</creator><creator>Norman, Vanessa L</creator><creator>Goering, Matt G</creator><creator>O’Neil-Johnson, Mark</creator><creator>Woodbury, Scott</creator><creator>Albrecht, Matthew A</creator><creator>Powell, Douglas R</creator><creator>Cichewicz, Robert H</creator><creator>Eldridge, Gary R</creator><creator>Starks, Courtney M</creator><general>American Chemical Society and American Society of Pharmacognosy</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20140627</creationdate><title>Diterpenes from the Endangered Goldenrod Solidago shortii</title><author>Williams, Russell B ; Du, Lin ; Norman, Vanessa L ; Goering, Matt G ; O’Neil-Johnson, Mark ; Woodbury, Scott ; Albrecht, Matthew A ; Powell, Douglas R ; Cichewicz, Robert H ; Eldridge, Gary R ; Starks, Courtney M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a315t-848cadf8a1befb5c5cabf9c487540b4b472f3b18e32b56fd3ce364f09ce101ba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Crystallography, X-Ray</topic><topic>Diterpenes - chemistry</topic><topic>Diterpenes - isolation & purification</topic><topic>Endangered Species</topic><topic>Missouri</topic><topic>Molecular Conformation</topic><topic>Molecular Structure</topic><topic>Nuclear Magnetic Resonance, Biomolecular</topic><topic>Solidago - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Williams, Russell B</creatorcontrib><creatorcontrib>Du, Lin</creatorcontrib><creatorcontrib>Norman, Vanessa L</creatorcontrib><creatorcontrib>Goering, Matt G</creatorcontrib><creatorcontrib>O’Neil-Johnson, Mark</creatorcontrib><creatorcontrib>Woodbury, Scott</creatorcontrib><creatorcontrib>Albrecht, Matthew A</creatorcontrib><creatorcontrib>Powell, Douglas R</creatorcontrib><creatorcontrib>Cichewicz, Robert H</creatorcontrib><creatorcontrib>Eldridge, Gary R</creatorcontrib><creatorcontrib>Starks, Courtney M</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of natural products (Washington, D.C.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Williams, Russell B</au><au>Du, Lin</au><au>Norman, Vanessa L</au><au>Goering, Matt G</au><au>O’Neil-Johnson, Mark</au><au>Woodbury, Scott</au><au>Albrecht, Matthew A</au><au>Powell, Douglas R</au><au>Cichewicz, Robert H</au><au>Eldridge, Gary R</au><au>Starks, Courtney M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diterpenes from the Endangered Goldenrod Solidago shortii</atitle><jtitle>Journal of natural products (Washington, D.C.)</jtitle><addtitle>J. Nat. Prod</addtitle><date>2014-06-27</date><risdate>2014</risdate><volume>77</volume><issue>6</issue><spage>1438</spage><epage>1444</epage><pages>1438-1444</pages><issn>0163-3864</issn><eissn>1520-6025</eissn><abstract>Species extinction is tantamount to loss of chemical diversity, and so it is important to seize all opportunities to study species on the brink of extinction. Such studies are often hampered by the limited material available, but that obstacle is surmountable through collaboration with botanical gardens and advances in instrumentation. The goldenrod Solidago shortii is one example of an endangered species native to the United States. From S. shortii, one known diterpene (1), two new diterpenes (2 and 3), and three new hydrolysis products (4–6) are described. This work was made possible through collaboration with the Missouri Botanical Garden and with the use of highly sensitive microcryoprobe NMR technology for structure elucidation and VCD spectroscopy for the determination of absolute configuration.</abstract><cop>United States</cop><pub>American Chemical Society and American Society of Pharmacognosy</pub><pmid>24922615</pmid><doi>10.1021/np500178s</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0163-3864 |
| ispartof | Journal of natural products (Washington, D.C.), 2014-06, Vol.77 (6), p.1438-1444 |
| issn | 0163-3864 1520-6025 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1541382960 |
| source | MEDLINE; American Chemical Society Publications |
| subjects | Crystallography, X-Ray Diterpenes - chemistry Diterpenes - isolation & purification Endangered Species Missouri Molecular Conformation Molecular Structure Nuclear Magnetic Resonance, Biomolecular Solidago - chemistry |
| title | Diterpenes from the Endangered Goldenrod Solidago shortii |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T19%3A44%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Diterpenes%20from%20the%20Endangered%20Goldenrod%20Solidago%20shortii&rft.jtitle=Journal%20of%20natural%20products%20(Washington,%20D.C.)&rft.au=Williams,%20Russell%20B&rft.date=2014-06-27&rft.volume=77&rft.issue=6&rft.spage=1438&rft.epage=1444&rft.pages=1438-1444&rft.issn=0163-3864&rft.eissn=1520-6025&rft_id=info:doi/10.1021/np500178s&rft_dat=%3Cproquest_cross%3E1541382960%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1541382960&rft_id=info:pmid/24922615&rfr_iscdi=true |