Temperature-dependent spin-state equilibrium in aquo and hydroxo ferric heme octapeptide complexes. Model systems for the spin equilibrium of ferric hemoproteins

The temperature dependencies of the magnetic susceptibilities of aquo and hydroxo ferric heme octapeptide complexes were investigated as models for the temperature-dependent spin-state equilibria of ferric hemoproteins. The shifts in proton NMR signal of the sodium 4,4-dimethy1-4-silapentanesulfonat...

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Veröffentlicht in:	Journal of the American Chemical Society 1981-08, Vol.103 (16), p.4927-4932
Hauptverfasser:	Huang, Ya-Ping, Kassner, Richard J
Format:	Artikel
Sprache:	eng
Schlagworte:	heme N.M.R peptides
Online-Zugang:	Volltext
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