DABCO-mediated isocyanide-based multicomponent reaction: synthesis of highly substituted cyclopentenes

DABCO-mediated isocyanide-based multicomponent reaction: synthesis of highly substituted cyclopentenes

Highly substituted cyclopentenes can be accessed rapidly from isocyanides, aldehydes and malononitrile or ethyl cyanoacetate (AB2C2) using DABCO as a catalyst under solvent-free conditions at 40 °C within 30 min.

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Veröffentlicht in:Organic & biomolecular chemistry 2014-07, Vol.12 (26), p.4628-4632
Hauptverfasser: Wen, Li-Rong, Lan, Ming-Chao, Yuan, Wen-Kui, Li, Ming
Format: Artikel
Sprache:eng
Schlagworte:
Biological Products - chemistry
Cyanides - chemistry
Cyclopentanes - chemical synthesis
Cyclopentanes - chemistry
Piperazines - chemistry
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container_end_page 4632
container_issue 26
container_start_page 4628
container_title Organic & biomolecular chemistry
container_volume 12
creator Wen, Li-Rong
Lan, Ming-Chao
Yuan, Wen-Kui
Li, Ming
description Highly substituted cyclopentenes can be accessed rapidly from isocyanides, aldehydes and malononitrile or ethyl cyanoacetate (AB2C2) using DABCO as a catalyst under solvent-free conditions at 40 °C within 30 min.
doi_str_mv 10.1039/c4ob00012a
format Article
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Biological Products - chemistry
Cyanides - chemistry
Cyclopentanes - chemical synthesis
Cyclopentanes - chemistry
Piperazines - chemistry
title DABCO-mediated isocyanide-based multicomponent reaction: synthesis of highly substituted cyclopentenes
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