Persistence and fate of deltamethrin sprayed on a pond
When sprayed on a pond in Prince Edward Island, Canada, deltamethrin disappeared quickly from water with a half-life of about one hour. Major routes of degradation and dissipation were chemical and photochemical conversion to inactive deltamethrin stereoisomers, and hydrolysis with subsequent oxidat...
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| Veröffentlicht in: | Journal of agricultural and food chemistry 1989-07, Vol.37 (4), p.1153-1159 |
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| container_end_page | 1159 |
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| container_issue | 4 |
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| container_title | Journal of agricultural and food chemistry |
| container_volume | 37 |
| creator | Maguire, R. James Carey, John H. Hart, James H. Tkacz, Richard J. Lee, Hing Biu |
| description | When sprayed on a pond in Prince Edward Island, Canada, deltamethrin disappeared quickly from water with a half-life of about one hour. Major routes of degradation and dissipation were chemical and photochemical conversion to inactive deltamethrin stereoisomers, and hydrolysis with subsequent oxidation of products. No deltamethrin stereoisomer residues or any of the four major degradation products sought were found 11 days post-spray. Laboratory analyses of the volatilization of deltamethrin formulations from sprayed water as opposed to subsurface-injected water indicated that volatilization from the surface microlayer was a rapid process that could be the major route of dissipation. |
| doi_str_mv | 10.1021/jf00088a074 |
| format | Article |
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James ; Carey, John H. ; Hart, James H. ; Tkacz, Richard J. ; Lee, Hing Biu</creator><creatorcontrib>Maguire, R. James ; Carey, John H. ; Hart, James H. ; Tkacz, Richard J. ; Lee, Hing Biu ; Canada Centre for Inland Waters, Burlington, Ontario, Canada ; Miljoestyrelsen, Copenhagen (Denmark)</creatorcontrib><description>When sprayed on a pond in Prince Edward Island, Canada, deltamethrin disappeared quickly from water with a half-life of about one hour. Major routes of degradation and dissipation were chemical and photochemical conversion to inactive deltamethrin stereoisomers, and hydrolysis with subsequent oxidation of products. No deltamethrin stereoisomer residues or any of the four major degradation products sought were found 11 days post-spray. Laboratory analyses of the volatilization of deltamethrin formulations from sprayed water as opposed to subsurface-injected water indicated that volatilization from the surface microlayer was a rapid process that could be the major route of dissipation.</description><identifier>ISSN: 0021-8561</identifier><identifier>EISSN: 1520-5118</identifier><identifier>DOI: 10.1021/jf00088a074</identifier><identifier>CODEN: JAFCAU</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Agronomy. Soil science and plant productions ; Animal, plant and microbial ecology ; Applied ecology ; Biological and medical sciences ; Ecotoxicology, biological effects of pollution ; estanques ; etang ; Fresh water environment ; Fundamental and applied biological sciences. Psychology ; insecticidas ; insecticide ; insecticides ; persistance des pesticides ; persistencia de los plaguicidas ; pesticide persistence ; ponds ; Soil and water pollution ; Soil science</subject><ispartof>Journal of agricultural and food chemistry, 1989-07, Vol.37 (4), p.1153-1159</ispartof><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a415t-c9754a4c5ecfbffb1dce4ca4d6adbd4f08df49bd6e4d2c73c745faec6f816db33</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jf00088a074$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jf00088a074$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7363751$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Maguire, R. James</creatorcontrib><creatorcontrib>Carey, John H.</creatorcontrib><creatorcontrib>Hart, James H.</creatorcontrib><creatorcontrib>Tkacz, Richard J.</creatorcontrib><creatorcontrib>Lee, Hing Biu</creatorcontrib><creatorcontrib>Canada Centre for Inland Waters, Burlington, Ontario, Canada</creatorcontrib><creatorcontrib>Miljoestyrelsen, Copenhagen (Denmark)</creatorcontrib><title>Persistence and fate of deltamethrin sprayed on a pond</title><title>Journal of agricultural and food chemistry</title><addtitle>J. Agric. Food Chem</addtitle><description>When sprayed on a pond in Prince Edward Island, Canada, deltamethrin disappeared quickly from water with a half-life of about one hour. Major routes of degradation and dissipation were chemical and photochemical conversion to inactive deltamethrin stereoisomers, and hydrolysis with subsequent oxidation of products. No deltamethrin stereoisomer residues or any of the four major degradation products sought were found 11 days post-spray. Laboratory analyses of the volatilization of deltamethrin formulations from sprayed water as opposed to subsurface-injected water indicated that volatilization from the surface microlayer was a rapid process that could be the major route of dissipation.</description><subject>Agronomy. Soil science and plant productions</subject><subject>Animal, plant and microbial ecology</subject><subject>Applied ecology</subject><subject>Biological and medical sciences</subject><subject>Ecotoxicology, biological effects of pollution</subject><subject>estanques</subject><subject>etang</subject><subject>Fresh water environment</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>insecticidas</subject><subject>insecticide</subject><subject>insecticides</subject><subject>persistance des pesticides</subject><subject>persistencia de los plaguicidas</subject><subject>pesticide persistence</subject><subject>ponds</subject><subject>Soil and water pollution</subject><subject>Soil science</subject><issn>0021-8561</issn><issn>1520-5118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNqF0M1LwzAYBvAgCs7pybv0IHqQatImTXuU6aYwcNrt4iW8zYd2du1MOnD_vSkd4kHwlMP7y5M3D0KnBF8THJGbpcEYpylgTvfQgLAIh4yQdB8NsB-HKUvIITpybtkxxvEAJTNtXelaXUsdQK0CA60OGhMoXbWw0u27LevArS1stQqaOoBg3dTqGB0YqJw-2Z1DtBjfz0cP4fRp8ji6nYZACWtDmXFGgUqmpSmMKYiSmkqgKgFVKGpwqgzNCpVoqiLJY8kpM6BlYlKSqCKOh-iiz13b5nOjXStWpZO6qqDWzcYJwuLYv5H9D2kU-z9zD696KG3jnNVGrG25ArsVBIuuRPGrRK_Pd7HgJFTGQi1L93OFx0nMGfEs7FnX5NfPGOyHSLgXYj7LBX59HueTlzuRe3_WewONgDfrIxc5ydIM-z1p1gVe9gCkE8tmY2vf8p8bfgOdPZZU</recordid><startdate>19890701</startdate><enddate>19890701</enddate><creator>Maguire, R. James</creator><creator>Carey, John H.</creator><creator>Hart, James H.</creator><creator>Tkacz, Richard J.</creator><creator>Lee, Hing Biu</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7T2</scope><scope>7TV</scope><scope>7U2</scope></search><sort><creationdate>19890701</creationdate><title>Persistence and fate of deltamethrin sprayed on a pond</title><author>Maguire, R. James ; Carey, John H. ; Hart, James H. ; Tkacz, Richard J. ; Lee, Hing Biu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a415t-c9754a4c5ecfbffb1dce4ca4d6adbd4f08df49bd6e4d2c73c745faec6f816db33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Agronomy. Soil science and plant productions</topic><topic>Animal, plant and microbial ecology</topic><topic>Applied ecology</topic><topic>Biological and medical sciences</topic><topic>Ecotoxicology, biological effects of pollution</topic><topic>estanques</topic><topic>etang</topic><topic>Fresh water environment</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>insecticidas</topic><topic>insecticide</topic><topic>insecticides</topic><topic>persistance des pesticides</topic><topic>persistencia de los plaguicidas</topic><topic>pesticide persistence</topic><topic>ponds</topic><topic>Soil and water pollution</topic><topic>Soil science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maguire, R. James</creatorcontrib><creatorcontrib>Carey, John H.</creatorcontrib><creatorcontrib>Hart, James H.</creatorcontrib><creatorcontrib>Tkacz, Richard J.</creatorcontrib><creatorcontrib>Lee, Hing Biu</creatorcontrib><creatorcontrib>Canada Centre for Inland Waters, Burlington, Ontario, Canada</creatorcontrib><creatorcontrib>Miljoestyrelsen, Copenhagen (Denmark)</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Pollution Abstracts</collection><collection>Safety Science and Risk</collection><jtitle>Journal of agricultural and food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maguire, R. James</au><au>Carey, John H.</au><au>Hart, James H.</au><au>Tkacz, Richard J.</au><au>Lee, Hing Biu</au><aucorp>Canada Centre for Inland Waters, Burlington, Ontario, Canada</aucorp><aucorp>Miljoestyrelsen, Copenhagen (Denmark)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Persistence and fate of deltamethrin sprayed on a pond</atitle><jtitle>Journal of agricultural and food chemistry</jtitle><addtitle>J. Agric. Food Chem</addtitle><date>1989-07-01</date><risdate>1989</risdate><volume>37</volume><issue>4</issue><spage>1153</spage><epage>1159</epage><pages>1153-1159</pages><issn>0021-8561</issn><eissn>1520-5118</eissn><coden>JAFCAU</coden><abstract>When sprayed on a pond in Prince Edward Island, Canada, deltamethrin disappeared quickly from water with a half-life of about one hour. Major routes of degradation and dissipation were chemical and photochemical conversion to inactive deltamethrin stereoisomers, and hydrolysis with subsequent oxidation of products. No deltamethrin stereoisomer residues or any of the four major degradation products sought were found 11 days post-spray. Laboratory analyses of the volatilization of deltamethrin formulations from sprayed water as opposed to subsurface-injected water indicated that volatilization from the surface microlayer was a rapid process that could be the major route of dissipation.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/jf00088a074</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0021-8561 |
| ispartof | Journal of agricultural and food chemistry, 1989-07, Vol.37 (4), p.1153-1159 |
| issn | 0021-8561 1520-5118 |
| language | eng |
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| source | ACS Publications |
| subjects | Agronomy. Soil science and plant productions Animal, plant and microbial ecology Applied ecology Biological and medical sciences Ecotoxicology, biological effects of pollution estanques etang Fresh water environment Fundamental and applied biological sciences. Psychology insecticidas insecticide insecticides persistance des pesticides persistencia de los plaguicidas pesticide persistence ponds Soil and water pollution Soil science |
| title | Persistence and fate of deltamethrin sprayed on a pond |
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