Expanded graphite as superior anode for sodium-ion batteries

Graphite, as the most common anode for commercial Li-ion batteries, has been reported to have a very low capacity when used as a Na-ion battery anode. It is well known that electrochemical insertion of Na + into graphite is significantly hindered by the insufficient interlayer spacing. Here we report expanded graphite as a Na-ion battery anode. Prepared through a process of oxidation and partial reduction on graphite, expanded graphite has an enlarged interlayer lattice distance of 4.3 Å yet retains an analogous long-range-ordered layered structure to graphite. In situ transmission electron microscopy has demonstrated that the Na-ion can be reversibly inserted into and extracted from expanded graphite. Galvanostatic studies show that expanded graphite can deliver a high reversible capacity of 284 mAh g −1 at a current density of 20 mA g −1 , maintain a capacity of 184 mAh g −1 at 100 mA g −1 , and retain 73.92% of its capacity after 2,000 cycles. Graphite is a common anode material for lithium-ion batteries, but small interlayer spacing makes it unsuitable for sodium-ion batteries. Here, Wen et al. synthesize a graphite material with expanded layer distances, which could be a promising anodic material for sodium-ion batteries.