ADMET reactions in miniemulsion
ABSTRACT This work investigates acyclic diene metathesis (ADMET) polymerization reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. A Ru‐indenylidene catalyst (Umicore M2) showed higher activity i...
Gespeichert in:
| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2014-05, Vol.52 (9), p.1300-1305 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1305 |
|---|---|
| container_issue | 9 |
| container_start_page | 1300 |
| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 52 |
| creator | Cardoso, Priscilla B. Musyanovych, Anna Landfester, Katharina Sayer, Claudia de Araújo, Pedro H. H. Meier, Michael A. R. |
| description | ABSTRACT
This work investigates acyclic diene metathesis (ADMET) polymerization reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. A Ru‐indenylidene catalyst (Umicore M2) showed higher activity in water if compared to the Ru‐benzylidene catalysts (Hoveyda Grubbs second generation and Grubbs first generation). Moreover, the catalyst activity was affected by the type of the surfactant. In summary, the Umicore M2 catalyst and the nonionic poly(ethylene oxide) based surfactant Lutensol AT80 were found to be the most suitable combination for ADMET reactions in miniemulsion allowing the preparation of polymers with number average molecular weight (Mn) of up to 15 kDa. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1300–1305
A 100% renewable monomer was polymerized via acyclic diene metathesis (ADMET) reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. Polymeric nanoparticles were successfully obtained with Mn of up to 15 kDa. |
| doi_str_mv | 10.1002/pola.27118 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1531020871</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1531020871</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4678-e97a5ad216d689766195f2060e27052b3f672ee2d5dac28a588b3866f3dba1623</originalsourceid><addsrcrecordid>eNp9kF1PwjAUhhujiYje-AckMSbGZNqerV-XiMAMKF5g9K4pW5cUx4Yti_LvHQ658IKrJqfP-5yTF6Fzgm8JxnC3LHN9C5wQcYBaBEsZYErEIWphIXjAIHo_RifezzGu_6hooYvuw1N_2nFGJytbFr5ji87CFtYsqtzXg1N0lOncm7Pt20avg_60FwfjyfCx1x0HScS4CIzkmuoUCEuZkJwxImkGmGEDHFOYhRnjYAykNNUJCE2FmIWCsSxMZ5owCNvouvEuXflZGb9SC-sTk-e6MGXlFaEhwYAFJzV6-Q-dl5Ur6usUUCxBAhd0H0VqigqQDNfUTUMlrvTemUwtnV1ot1YEq02jatOo-m20hq-2Su0TnWdOF4n1uwSIKIwisllNGu7L5ma9x6heJuPunztoMtavzPcuo92HYjzkVL09D1UUj-JBPLpXg_AHvNqQKw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1509582960</pqid></control><display><type>article</type><title>ADMET reactions in miniemulsion</title><source>Access via Wiley Online Library</source><creator>Cardoso, Priscilla B. ; Musyanovych, Anna ; Landfester, Katharina ; Sayer, Claudia ; de Araújo, Pedro H. H. ; Meier, Michael A. R.</creator><creatorcontrib>Cardoso, Priscilla B. ; Musyanovych, Anna ; Landfester, Katharina ; Sayer, Claudia ; de Araújo, Pedro H. H. ; Meier, Michael A. R.</creatorcontrib><description>ABSTRACT
This work investigates acyclic diene metathesis (ADMET) polymerization reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. A Ru‐indenylidene catalyst (Umicore M2) showed higher activity in water if compared to the Ru‐benzylidene catalysts (Hoveyda Grubbs second generation and Grubbs first generation). Moreover, the catalyst activity was affected by the type of the surfactant. In summary, the Umicore M2 catalyst and the nonionic poly(ethylene oxide) based surfactant Lutensol AT80 were found to be the most suitable combination for ADMET reactions in miniemulsion allowing the preparation of polymers with number average molecular weight (Mn) of up to 15 kDa. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1300–1305
A 100% renewable monomer was polymerized via acyclic diene metathesis (ADMET) reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. Polymeric nanoparticles were successfully obtained with Mn of up to 15 kDa.</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.27118</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken, NJ: Blackwell Publishing Ltd</publisher><subject>ADMET ; Applied sciences ; castor oil ; Catalysis ; Catalysts ; Cationic ; Ethylene oxide ; Exact sciences and technology ; Manganese ; Metathesis ; miniemulsion polymerization ; nanoparticles ; Nonionic ; Organic polymers ; Physicochemistry of polymers ; Polyethylene oxide ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; renewable resources ; Ruthenium ; Surfactants</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2014-05, Vol.52 (9), p.1300-1305</ispartof><rights>Copyright © 2014 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4678-e97a5ad216d689766195f2060e27052b3f672ee2d5dac28a588b3866f3dba1623</citedby><cites>FETCH-LOGICAL-c4678-e97a5ad216d689766195f2060e27052b3f672ee2d5dac28a588b3866f3dba1623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.27118$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.27118$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28434415$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Cardoso, Priscilla B.</creatorcontrib><creatorcontrib>Musyanovych, Anna</creatorcontrib><creatorcontrib>Landfester, Katharina</creatorcontrib><creatorcontrib>Sayer, Claudia</creatorcontrib><creatorcontrib>de Araújo, Pedro H. H.</creatorcontrib><creatorcontrib>Meier, Michael A. R.</creatorcontrib><title>ADMET reactions in miniemulsion</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><description>ABSTRACT
This work investigates acyclic diene metathesis (ADMET) polymerization reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. A Ru‐indenylidene catalyst (Umicore M2) showed higher activity in water if compared to the Ru‐benzylidene catalysts (Hoveyda Grubbs second generation and Grubbs first generation). Moreover, the catalyst activity was affected by the type of the surfactant. In summary, the Umicore M2 catalyst and the nonionic poly(ethylene oxide) based surfactant Lutensol AT80 were found to be the most suitable combination for ADMET reactions in miniemulsion allowing the preparation of polymers with number average molecular weight (Mn) of up to 15 kDa. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1300–1305
A 100% renewable monomer was polymerized via acyclic diene metathesis (ADMET) reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. Polymeric nanoparticles were successfully obtained with Mn of up to 15 kDa.</description><subject>ADMET</subject><subject>Applied sciences</subject><subject>castor oil</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Cationic</subject><subject>Ethylene oxide</subject><subject>Exact sciences and technology</subject><subject>Manganese</subject><subject>Metathesis</subject><subject>miniemulsion polymerization</subject><subject>nanoparticles</subject><subject>Nonionic</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyethylene oxide</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>renewable resources</subject><subject>Ruthenium</subject><subject>Surfactants</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kF1PwjAUhhujiYje-AckMSbGZNqerV-XiMAMKF5g9K4pW5cUx4Yti_LvHQ658IKrJqfP-5yTF6Fzgm8JxnC3LHN9C5wQcYBaBEsZYErEIWphIXjAIHo_RifezzGu_6hooYvuw1N_2nFGJytbFr5ji87CFtYsqtzXg1N0lOncm7Pt20avg_60FwfjyfCx1x0HScS4CIzkmuoUCEuZkJwxImkGmGEDHFOYhRnjYAykNNUJCE2FmIWCsSxMZ5owCNvouvEuXflZGb9SC-sTk-e6MGXlFaEhwYAFJzV6-Q-dl5Ur6usUUCxBAhd0H0VqigqQDNfUTUMlrvTemUwtnV1ot1YEq02jatOo-m20hq-2Su0TnWdOF4n1uwSIKIwisllNGu7L5ma9x6heJuPunztoMtavzPcuo92HYjzkVL09D1UUj-JBPLpXg_AHvNqQKw</recordid><startdate>20140501</startdate><enddate>20140501</enddate><creator>Cardoso, Priscilla B.</creator><creator>Musyanovych, Anna</creator><creator>Landfester, Katharina</creator><creator>Sayer, Claudia</creator><creator>de Araújo, Pedro H. H.</creator><creator>Meier, Michael A. R.</creator><general>Blackwell Publishing Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140501</creationdate><title>ADMET reactions in miniemulsion</title><author>Cardoso, Priscilla B. ; Musyanovych, Anna ; Landfester, Katharina ; Sayer, Claudia ; de Araújo, Pedro H. H. ; Meier, Michael A. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4678-e97a5ad216d689766195f2060e27052b3f672ee2d5dac28a588b3866f3dba1623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>ADMET</topic><topic>Applied sciences</topic><topic>castor oil</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Cationic</topic><topic>Ethylene oxide</topic><topic>Exact sciences and technology</topic><topic>Manganese</topic><topic>Metathesis</topic><topic>miniemulsion polymerization</topic><topic>nanoparticles</topic><topic>Nonionic</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polyethylene oxide</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>renewable resources</topic><topic>Ruthenium</topic><topic>Surfactants</topic><toplevel>online_resources</toplevel><creatorcontrib>Cardoso, Priscilla B.</creatorcontrib><creatorcontrib>Musyanovych, Anna</creatorcontrib><creatorcontrib>Landfester, Katharina</creatorcontrib><creatorcontrib>Sayer, Claudia</creatorcontrib><creatorcontrib>de Araújo, Pedro H. H.</creatorcontrib><creatorcontrib>Meier, Michael A. R.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cardoso, Priscilla B.</au><au>Musyanovych, Anna</au><au>Landfester, Katharina</au><au>Sayer, Claudia</au><au>de Araújo, Pedro H. H.</au><au>Meier, Michael A. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ADMET reactions in miniemulsion</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. Part A: Polym. Chem</addtitle><date>2014-05-01</date><risdate>2014</risdate><volume>52</volume><issue>9</issue><spage>1300</spage><epage>1305</epage><pages>1300-1305</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>ABSTRACT
This work investigates acyclic diene metathesis (ADMET) polymerization reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. A Ru‐indenylidene catalyst (Umicore M2) showed higher activity in water if compared to the Ru‐benzylidene catalysts (Hoveyda Grubbs second generation and Grubbs first generation). Moreover, the catalyst activity was affected by the type of the surfactant. In summary, the Umicore M2 catalyst and the nonionic poly(ethylene oxide) based surfactant Lutensol AT80 were found to be the most suitable combination for ADMET reactions in miniemulsion allowing the preparation of polymers with number average molecular weight (Mn) of up to 15 kDa. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1300–1305
A 100% renewable monomer was polymerized via acyclic diene metathesis (ADMET) reactions in aqueous miniemulsion. Different types of ruthenium‐based catalysts and different surfactants (anionic, cationic, and nonionic) were evaluated. Polymeric nanoparticles were successfully obtained with Mn of up to 15 kDa.</abstract><cop>Hoboken, NJ</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/pola.27118</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0887-624X |
| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2014-05, Vol.52 (9), p.1300-1305 |
| issn | 0887-624X 1099-0518 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1531020871 |
| source | Access via Wiley Online Library |
| subjects | ADMET Applied sciences castor oil Catalysis Catalysts Cationic Ethylene oxide Exact sciences and technology Manganese Metathesis miniemulsion polymerization nanoparticles Nonionic Organic polymers Physicochemistry of polymers Polyethylene oxide Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts renewable resources Ruthenium Surfactants |
| title | ADMET reactions in miniemulsion |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-20T09%3A57%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=ADMET%20reactions%20in%20miniemulsion&rft.jtitle=Journal%20of%20polymer%20science.%20Part%20A,%20Polymer%20chemistry&rft.au=Cardoso,%20Priscilla%20B.&rft.date=2014-05-01&rft.volume=52&rft.issue=9&rft.spage=1300&rft.epage=1305&rft.pages=1300-1305&rft.issn=0887-624X&rft.eissn=1099-0518&rft.coden=JPLCAT&rft_id=info:doi/10.1002/pola.27118&rft_dat=%3Cproquest_cross%3E1531020871%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1509582960&rft_id=info:pmid/&rfr_iscdi=true |