Thermodynamic and electrochemical study on the mechanism of formation of Ag(OH)4− in alkaline media

•Sensitive electrochemical techniques were used to evidence the formation of Ag(III).•The required potential for the generation of Ag(III) was found by using UV–vis to monitor species being formed.•A mechanism for the production of Ag(III) in the form of Ag(OH)4− is proposed. A mechanism based on el...

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Veröffentlicht in:	Electrochimica acta 2013-11, Vol.111, p.268-274
Hauptverfasser:	Zamora-Garcia, I.R., Alatorre-Ordaz, A., Ibanez, J.G., Garcia-Jimenez, M.G., Nosaka, Y., Kobayashi, T., Sugita, S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Decomposition Higher silver oxides Media Scanning electron microscopy Silver Pourbaix diagram Silver tetrahydroxoargentate Spectrophotometry Thermodynamics
Online-Zugang:	Volltext
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