Characterization of spray-coating methods for conjugated polymer blend thin films
We examine the characteristics and functionality of conjugated polymer thin films, based on blends of poly(9,9-dioctylfluorene-2,7-diyl- co -bis- N , NN ′-(4-butylphenyl)-bis- N , N ′-phenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-2,7-diyl- co -benzothiadiazole) (F8BT), using a spra...
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| Veröffentlicht in: | Journal of materials science 2014-06, Vol.49 (12), p.4279-4287 |
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| creator | Noebels, Matthias Cross, Rachel E. Evans, D. A. Finlayson, Chris E. |
| description | We examine the characteristics and functionality of conjugated polymer thin films, based on blends of poly(9,9-dioctylfluorene-2,7-diyl-
co
-bis-
N
,
NN
′-(4-butylphenyl)-bis-
N
,
N
′-phenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-2,7-diyl-
co
-benzothiadiazole) (F8BT), using a spray-coating deposition technique suitable for large areas. The morphological properties of these blend films are studied in detail by atomic force microscopy (AFM) methods, showing that favourable results, in terms of layer deposition rate and uniformity, can be achieved using a 5:1 blend of
o
-dichlorobenzene and chlorobenzene as the solvent medium. A photoluminescence quenching efficiency of above 80 % is also observed in such blend films. As a feasibility study, prototypical photovoltaic devices exhibit open circuit voltages of up to 1.0 V under testing, and solar power conversion efficiencies in the 0.1–1 % order of magnitude; metrics which are comparable with those reported for spin-coated cells of the same active blend and device architecture. |
| doi_str_mv | 10.1007/s10853-014-8123-5 |
| format | Article |
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co
-bis-
N
,
NN
′-(4-butylphenyl)-bis-
N
,
N
′-phenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-2,7-diyl-
co
-benzothiadiazole) (F8BT), using a spray-coating deposition technique suitable for large areas. The morphological properties of these blend films are studied in detail by atomic force microscopy (AFM) methods, showing that favourable results, in terms of layer deposition rate and uniformity, can be achieved using a 5:1 blend of
o
-dichlorobenzene and chlorobenzene as the solvent medium. A photoluminescence quenching efficiency of above 80 % is also observed in such blend films. As a feasibility study, prototypical photovoltaic devices exhibit open circuit voltages of up to 1.0 V under testing, and solar power conversion efficiencies in the 0.1–1 % order of magnitude; metrics which are comparable with those reported for spin-coated cells of the same active blend and device architecture.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-014-8123-5</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Analysis ; Atomic force microscopy ; Blends ; Characterization and Evaluation of Materials ; Chemical properties ; Chemistry and Materials Science ; Chlorobenzene ; Circuits ; Classical Mechanics ; Coatings ; Computer architecture ; Crystallography and Scattering Methods ; Deposition ; Devices ; Dichlorobenzene ; Dielectric films ; Energy conversion efficiency ; Feasibility studies ; Materials Science ; Methods ; Open circuit voltage ; Phenylenediamine ; Photoluminescence ; Photovoltaic cells ; Polymer blends ; Polymer films ; Polymer Sciences ; Polymers ; Solar cells ; Solar energy ; Solid Mechanics ; Spin coating ; Spray coating ; Thin films</subject><ispartof>Journal of materials science, 2014-06, Vol.49 (12), p.4279-4287</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>COPYRIGHT 2014 Springer</rights><rights>Journal of Materials Science is a copyright of Springer, (2014). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c572t-9a614e319e890fb6239bca29527d02604fee9a244ec68e3780d7c74c75f238d63</citedby><cites>FETCH-LOGICAL-c572t-9a614e319e890fb6239bca29527d02604fee9a244ec68e3780d7c74c75f238d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-014-8123-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-014-8123-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Noebels, Matthias</creatorcontrib><creatorcontrib>Cross, Rachel E.</creatorcontrib><creatorcontrib>Evans, D. A.</creatorcontrib><creatorcontrib>Finlayson, Chris E.</creatorcontrib><title>Characterization of spray-coating methods for conjugated polymer blend thin films</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>We examine the characteristics and functionality of conjugated polymer thin films, based on blends of poly(9,9-dioctylfluorene-2,7-diyl-
co
-bis-
N
,
NN
′-(4-butylphenyl)-bis-
N
,
N
′-phenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-2,7-diyl-
co
-benzothiadiazole) (F8BT), using a spray-coating deposition technique suitable for large areas. The morphological properties of these blend films are studied in detail by atomic force microscopy (AFM) methods, showing that favourable results, in terms of layer deposition rate and uniformity, can be achieved using a 5:1 blend of
o
-dichlorobenzene and chlorobenzene as the solvent medium. A photoluminescence quenching efficiency of above 80 % is also observed in such blend films. As a feasibility study, prototypical photovoltaic devices exhibit open circuit voltages of up to 1.0 V under testing, and solar power conversion efficiencies in the 0.1–1 % order of magnitude; metrics which are comparable with those reported for spin-coated cells of the same active blend and device architecture.</description><subject>Analysis</subject><subject>Atomic force microscopy</subject><subject>Blends</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemistry and Materials Science</subject><subject>Chlorobenzene</subject><subject>Circuits</subject><subject>Classical Mechanics</subject><subject>Coatings</subject><subject>Computer architecture</subject><subject>Crystallography and Scattering Methods</subject><subject>Deposition</subject><subject>Devices</subject><subject>Dichlorobenzene</subject><subject>Dielectric films</subject><subject>Energy conversion efficiency</subject><subject>Feasibility studies</subject><subject>Materials Science</subject><subject>Methods</subject><subject>Open circuit voltage</subject><subject>Phenylenediamine</subject><subject>Photoluminescence</subject><subject>Photovoltaic cells</subject><subject>Polymer blends</subject><subject>Polymer films</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Solar cells</subject><subject>Solar energy</subject><subject>Solid Mechanics</subject><subject>Spin coating</subject><subject>Spray coating</subject><subject>Thin films</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kU2LFDEQhoMoOK7-AG8BL3rIWvnqdB-XwY-FhcWvc8ikKzM9dHfGJA07_noztCArSA6B8LyVqnoIec3hmgOY95lDqyUDrljLhWT6CdlwbSRTLcinZAMgBBOq4c_Ji5yPAKCN4BvyZXtwyfmCafjlyhBnGgPNp-TOzMf6MO_phOUQ-0xDTNTH-bjsXcGenuJ4njDR3YhzT8thmGkYxim_JM-CGzO--nNfkR8fP3zffmZ3959utzd3zNefC-tcwxVK3mHbQdg1QnY770SnhelBNKACYueEUuibFqVpoTfeKG90ELLtG3lF3q51Tyn-XDAXOw3Z4zi6GeOSLdeybqY1oCv65h_0GJc01-6sELozsuMCKnW9Uns3oh3mEEvdTD09TkMdHOt4aG-k4bwDpS9l3z0KVKbgQ9m7JWd7--3rY5avrE8x54TBntIwuXS2HOzFoF0N2mrQXgzaS0asmeqjisD0t-3_h34DpdWb8w</recordid><startdate>20140601</startdate><enddate>20140601</enddate><creator>Noebels, Matthias</creator><creator>Cross, Rachel E.</creator><creator>Evans, D. A.</creator><creator>Finlayson, Chris E.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140601</creationdate><title>Characterization of spray-coating methods for conjugated polymer blend thin films</title><author>Noebels, Matthias ; Cross, Rachel E. ; Evans, D. A. ; Finlayson, Chris E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c572t-9a614e319e890fb6239bca29527d02604fee9a244ec68e3780d7c74c75f238d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Analysis</topic><topic>Atomic force microscopy</topic><topic>Blends</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical properties</topic><topic>Chemistry and Materials Science</topic><topic>Chlorobenzene</topic><topic>Circuits</topic><topic>Classical Mechanics</topic><topic>Coatings</topic><topic>Computer architecture</topic><topic>Crystallography and Scattering Methods</topic><topic>Deposition</topic><topic>Devices</topic><topic>Dichlorobenzene</topic><topic>Dielectric films</topic><topic>Energy conversion efficiency</topic><topic>Feasibility studies</topic><topic>Materials Science</topic><topic>Methods</topic><topic>Open circuit voltage</topic><topic>Phenylenediamine</topic><topic>Photoluminescence</topic><topic>Photovoltaic cells</topic><topic>Polymer blends</topic><topic>Polymer films</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Solar cells</topic><topic>Solar energy</topic><topic>Solid Mechanics</topic><topic>Spin coating</topic><topic>Spray coating</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noebels, Matthias</creatorcontrib><creatorcontrib>Cross, Rachel E.</creatorcontrib><creatorcontrib>Evans, D. 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A.</au><au>Finlayson, Chris E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of spray-coating methods for conjugated polymer blend thin films</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2014-06-01</date><risdate>2014</risdate><volume>49</volume><issue>12</issue><spage>4279</spage><epage>4287</epage><pages>4279-4287</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>We examine the characteristics and functionality of conjugated polymer thin films, based on blends of poly(9,9-dioctylfluorene-2,7-diyl-
co
-bis-
N
,
NN
′-(4-butylphenyl)-bis-
N
,
N
′-phenyl-1,4-phenylenediamine) (PFB) and poly(9,9-dioctylfluorene-2,7-diyl-
co
-benzothiadiazole) (F8BT), using a spray-coating deposition technique suitable for large areas. The morphological properties of these blend films are studied in detail by atomic force microscopy (AFM) methods, showing that favourable results, in terms of layer deposition rate and uniformity, can be achieved using a 5:1 blend of
o
-dichlorobenzene and chlorobenzene as the solvent medium. A photoluminescence quenching efficiency of above 80 % is also observed in such blend films. As a feasibility study, prototypical photovoltaic devices exhibit open circuit voltages of up to 1.0 V under testing, and solar power conversion efficiencies in the 0.1–1 % order of magnitude; metrics which are comparable with those reported for spin-coated cells of the same active blend and device architecture.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10853-014-8123-5</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of materials science, 2014-06, Vol.49 (12), p.4279-4287 |
| issn | 0022-2461 1573-4803 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Analysis Atomic force microscopy Blends Characterization and Evaluation of Materials Chemical properties Chemistry and Materials Science Chlorobenzene Circuits Classical Mechanics Coatings Computer architecture Crystallography and Scattering Methods Deposition Devices Dichlorobenzene Dielectric films Energy conversion efficiency Feasibility studies Materials Science Methods Open circuit voltage Phenylenediamine Photoluminescence Photovoltaic cells Polymer blends Polymer films Polymer Sciences Polymers Solar cells Solar energy Solid Mechanics Spin coating Spray coating Thin films |
| title | Characterization of spray-coating methods for conjugated polymer blend thin films |
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