Characterization and thermo physical property investigations on Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions
Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions were synthesized by complex polymerization method. The solid solutions were characterized using X-ray diffraction (XRD) and the Raman spectroscopy. Heat capacity measurements on Ba1−xSrxMoO4(s) were performed with heat flux-type different...
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| Veröffentlicht in: | Journal of nuclear materials 2012-08, Vol.427 (1-3), p.323-332 |
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| creator | Sahu, Manjulata Krishnan, K. Nagar, B.K. Jain, Dheeraj Saxena, M.K. Pillai, C.G.S. Dash, Smruti |
| description | Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions were synthesized by complex polymerization method. The solid solutions were characterized using X-ray diffraction (XRD) and the Raman spectroscopy. Heat capacity measurements on Ba1−xSrxMoO4(s) were performed with heat flux-type differential scanning calorimeter in the temperature range of 140–870K. The measured heat capacity values were used to calculate different thermodynamic functions such as enthalpy increment, entropy and Gibbs energy functions. Thermal expansion behavior of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) were investigated in the temperature range 298–1273K by high temperature X-ray diffraction (HTXRD). The specific heat and average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) was found to increase with increase in concentration of strontium. The average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) was found to be 25.59×10−6, 33.86×10−6 and 34.37×10−6K−1 respectively. |
| doi_str_mv | 10.1016/j.jnucmat.2012.04.025 |
| format | Article |
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The solid solutions were characterized using X-ray diffraction (XRD) and the Raman spectroscopy. Heat capacity measurements on Ba1−xSrxMoO4(s) were performed with heat flux-type differential scanning calorimeter in the temperature range of 140–870K. The measured heat capacity values were used to calculate different thermodynamic functions such as enthalpy increment, entropy and Gibbs energy functions. Thermal expansion behavior of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) were investigated in the temperature range 298–1273K by high temperature X-ray diffraction (HTXRD). The specific heat and average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) was found to increase with increase in concentration of strontium. The average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) was found to be 25.59×10−6, 33.86×10−6 and 34.37×10−6K−1 respectively.</description><identifier>ISSN: 0022-3115</identifier><identifier>EISSN: 1873-4820</identifier><identifier>DOI: 10.1016/j.jnucmat.2012.04.025</identifier><identifier>CODEN: JNUMAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Controled nuclear fusion plants ; Diffraction ; Energy ; Energy. Thermal use of fuels ; Entropy ; Exact sciences and technology ; Fission nuclear power plants ; Fuels ; Heat capacity ; Installations for energy generation and conversion: thermal and electrical energy ; Nuclear fuels ; Physical properties ; Solid solutions ; Specific heat ; Thermal expansion ; X-rays</subject><ispartof>Journal of nuclear materials, 2012-08, Vol.427 (1-3), p.323-332</ispartof><rights>2012 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c302t-c5ae550d749f2ab04ff3ab35b235cc61518ec47988d4bd47e37016a70ea8bcbd3</citedby><cites>FETCH-LOGICAL-c302t-c5ae550d749f2ab04ff3ab35b235cc61518ec47988d4bd47e37016a70ea8bcbd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jnucmat.2012.04.025$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=26117753$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sahu, Manjulata</creatorcontrib><creatorcontrib>Krishnan, K.</creatorcontrib><creatorcontrib>Nagar, B.K.</creatorcontrib><creatorcontrib>Jain, Dheeraj</creatorcontrib><creatorcontrib>Saxena, M.K.</creatorcontrib><creatorcontrib>Pillai, C.G.S.</creatorcontrib><creatorcontrib>Dash, Smruti</creatorcontrib><title>Characterization and thermo physical property investigations on Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions</title><title>Journal of nuclear materials</title><description>Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions were synthesized by complex polymerization method. The solid solutions were characterized using X-ray diffraction (XRD) and the Raman spectroscopy. Heat capacity measurements on Ba1−xSrxMoO4(s) were performed with heat flux-type differential scanning calorimeter in the temperature range of 140–870K. The measured heat capacity values were used to calculate different thermodynamic functions such as enthalpy increment, entropy and Gibbs energy functions. Thermal expansion behavior of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) were investigated in the temperature range 298–1273K by high temperature X-ray diffraction (HTXRD). The specific heat and average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) was found to increase with increase in concentration of strontium. The average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) was found to be 25.59×10−6, 33.86×10−6 and 34.37×10−6K−1 respectively.</description><subject>Applied sciences</subject><subject>Controled nuclear fusion plants</subject><subject>Diffraction</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Entropy</subject><subject>Exact sciences and technology</subject><subject>Fission nuclear power plants</subject><subject>Fuels</subject><subject>Heat capacity</subject><subject>Installations for energy generation and conversion: thermal and electrical energy</subject><subject>Nuclear fuels</subject><subject>Physical properties</subject><subject>Solid solutions</subject><subject>Specific heat</subject><subject>Thermal expansion</subject><subject>X-rays</subject><issn>0022-3115</issn><issn>1873-4820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqFkMuKFDEUhoMo2I4-gpCNMMJUeXLrSi1EtJlRYWQW6jqcSp2y01RXtUn10O3GrWsf0ScxfcGtmxMI37n8H2PPBZQCxPzVqlwNW7_GqZQgZAm6BGkesJmwlSq0lfCQzQCkLJQQ5jF7ktIKAEwNZsZ-LpYY0U8Uww-cwjhwHFo-LSmuR75Z7lPw2PNNHDcUpz0Pwz2lKXw7ooln_B2KP79-7z7H3afxTvPL3Wu44vkwe6jqWOfHHyuuuHjJ09iHtsh1exzxlD3qsE_07PxesK83118WH4rbu_cfF29vC69AToU3SMZAW-m6k9iA7jqFjTKNVMb7uTDCktdVbW2rm1ZXpKpsBisgtI1vWnXBLk9zc5Tv25zBrUPy1Pc40LhNThgFdQ3a6oyaE-rjmFKkzm1iWGPcOwHuINyt3Fm4Owh3oF0WnvtenFdgytK6iIMP6V-znAtRVUZl7s2Jo5z3PlB0yQcaPLUhkp9cO4b_bPoL4YWXeA</recordid><startdate>20120801</startdate><enddate>20120801</enddate><creator>Sahu, Manjulata</creator><creator>Krishnan, K.</creator><creator>Nagar, B.K.</creator><creator>Jain, Dheeraj</creator><creator>Saxena, M.K.</creator><creator>Pillai, C.G.S.</creator><creator>Dash, Smruti</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20120801</creationdate><title>Characterization and thermo physical property investigations on Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions</title><author>Sahu, Manjulata ; Krishnan, K. ; Nagar, B.K. ; Jain, Dheeraj ; Saxena, M.K. ; Pillai, C.G.S. ; Dash, Smruti</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c302t-c5ae550d749f2ab04ff3ab35b235cc61518ec47988d4bd47e37016a70ea8bcbd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Controled nuclear fusion plants</topic><topic>Diffraction</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Entropy</topic><topic>Exact sciences and technology</topic><topic>Fission nuclear power plants</topic><topic>Fuels</topic><topic>Heat capacity</topic><topic>Installations for energy generation and conversion: thermal and electrical energy</topic><topic>Nuclear fuels</topic><topic>Physical properties</topic><topic>Solid solutions</topic><topic>Specific heat</topic><topic>Thermal expansion</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sahu, Manjulata</creatorcontrib><creatorcontrib>Krishnan, K.</creatorcontrib><creatorcontrib>Nagar, B.K.</creatorcontrib><creatorcontrib>Jain, Dheeraj</creatorcontrib><creatorcontrib>Saxena, M.K.</creatorcontrib><creatorcontrib>Pillai, C.G.S.</creatorcontrib><creatorcontrib>Dash, Smruti</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sahu, Manjulata</au><au>Krishnan, K.</au><au>Nagar, B.K.</au><au>Jain, Dheeraj</au><au>Saxena, M.K.</au><au>Pillai, C.G.S.</au><au>Dash, Smruti</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization and thermo physical property investigations on Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions</atitle><jtitle>Journal of nuclear materials</jtitle><date>2012-08-01</date><risdate>2012</risdate><volume>427</volume><issue>1-3</issue><spage>323</spage><epage>332</epage><pages>323-332</pages><issn>0022-3115</issn><eissn>1873-4820</eissn><coden>JNUMAM</coden><abstract>Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions were synthesized by complex polymerization method. The solid solutions were characterized using X-ray diffraction (XRD) and the Raman spectroscopy. Heat capacity measurements on Ba1−xSrxMoO4(s) were performed with heat flux-type differential scanning calorimeter in the temperature range of 140–870K. The measured heat capacity values were used to calculate different thermodynamic functions such as enthalpy increment, entropy and Gibbs energy functions. Thermal expansion behavior of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) were investigated in the temperature range 298–1273K by high temperature X-ray diffraction (HTXRD). The specific heat and average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) was found to increase with increase in concentration of strontium. The average volume thermal expansion coefficient of Ba1−xSrxMoO4(s) (x=0, 0.6 and 1) was found to be 25.59×10−6, 33.86×10−6 and 34.37×10−6K−1 respectively.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnucmat.2012.04.025</doi><tpages>10</tpages></addata></record> |
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| subjects | Applied sciences Controled nuclear fusion plants Diffraction Energy Energy. Thermal use of fuels Entropy Exact sciences and technology Fission nuclear power plants Fuels Heat capacity Installations for energy generation and conversion: thermal and electrical energy Nuclear fuels Physical properties Solid solutions Specific heat Thermal expansion X-rays |
| title | Characterization and thermo physical property investigations on Ba1−xSrxMoO4 (x=0, 0.18, 0.38, 0.60, 0.81, 1) solid-solutions |
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