Morphology controllable and highly luminescent monoclinic LaPO4:Eu3+ microspheres

•Morphology controllable LaPO4:Eu3+ microspheres are prepared by a facile but effective two-step way.•An enhanced luminescent intensity was obtained from the resulting microspheres.•The luminescent performance of the resulting microspheres is comparable to the bulk materials. A facile, but effective...

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Veröffentlicht in:Journal of alloys and compounds 2014-01, Vol.582, p.603-608
Hauptverfasser: Yang, Mei, You, Hongpeng, Liang, Youlong, Xu, Jingzhou, Lu, Fan, Dai, Liming, Liu, Yong
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container_end_page 608
container_issue
container_start_page 603
container_title Journal of alloys and compounds
container_volume 582
creator Yang, Mei
You, Hongpeng
Liang, Youlong
Xu, Jingzhou
Lu, Fan
Dai, Liming
Liu, Yong
description •Morphology controllable LaPO4:Eu3+ microspheres are prepared by a facile but effective two-step way.•An enhanced luminescent intensity was obtained from the resulting microspheres.•The luminescent performance of the resulting microspheres is comparable to the bulk materials. A facile, but effective, two-step method was developed to prepare monoclinic LaPO4:Eu3+ microspheres composed of microprisms with a controllable morphology. XRD and SEM studies revealed a spherical morphology and crystalline structure for the resulting material. It was also found that LaPO4:Eu3+ microspheres prepared at 800°C showed a higher luminescent intensity than primary hexagonal LaPO4:Eu3+ microprisms. Furthermore, the luminescent performance of LaPO4:Eu3+ microspheres was demonstrated to reach the standards of the LaPO4:Eu3+ bulk material under the same conditions. These results suggest possibilities for the use of as-synthesized monoclinic LaPO4:Eu3+ microspheres as alternatives to replace intrinsically uneven bulk materials for many application areas, including light display systems and optoelectronic devices.
doi_str_mv 10.1016/j.jallcom.2013.08.091
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subjects Alloys
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Controllable morphology
Crystal structure
Exact sciences and technology
Highly luminescence
LaPO4:Eu3+ microspheres
Microspheres
Morphology
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical properties of specific thin films
Optoelectronic devices
Physics
Scanning electron microscopy
Stability
title Morphology controllable and highly luminescent monoclinic LaPO4:Eu3+ microspheres
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