Heterodinuclear complexes of 4,5-diazafluorene derivatives displaying η(5),κ(2)-[N,N] and η(5),κ(1)-N coordination modes

Heterodinuclear complexes of 4,5-diazafluorene derivatives displaying η(5),κ(2)-[N,N] and η(5),κ(1)-N coordination modes

The syntheses and structures for a series of heterodinuclear complexes of 4,5-diazafluorenyl (L(-)) and 3,6-dimesityl-4,5-diazafluorenyl (LMes(-)) ligands are reported herein. In all these heterodinuclear complexes, the Ru(II) centre is sandwiched between a pentamethylcyclopentadienyl (Cp*) ligand a...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2014-06, Vol.43 (23), p.8951-8958
Hauptverfasser: Batcup, Rhys, Annibale, Vincent T, Song, Datong
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Batcup, Rhys
Annibale, Vincent T
Song, Datong
description The syntheses and structures for a series of heterodinuclear complexes of 4,5-diazafluorenyl (L(-)) and 3,6-dimesityl-4,5-diazafluorenyl (LMes(-)) ligands are reported herein. In all these heterodinuclear complexes, the Ru(II) centre is sandwiched between a pentamethylcyclopentadienyl (Cp*) ligand and the C5 ring of L(-) or LMes(-) in a double η(5) fashion, while the other metal (Fe(II), Co(II), Pt(II), or Cu(I)) is bound to the N-donors.
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title Heterodinuclear complexes of 4,5-diazafluorene derivatives displaying η(5),κ(2)-[N,N] and η(5),κ(1)-N coordination modes
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