Mild Solvothermal Syntheses and Characterization of Layered Copper Thioantimonates(III) and Thioarsenate(III)

Mild Solvothermal Syntheses and Characterization of Layered Copper Thioantimonates(III) and Thioarsenate(III)

The new copper thioantimonates(III) and thioarsenate(III) Rb2Cu2Sb2S5 (1), Cs2Cu2Sb2S5 (2), and Rb8Cu6As8S19 (3) have been synthesized solvothermally. Compound 1 contains a [Cu2SbS3] net to which [Sb2S4] chains adhere through Cu–S bonds and Sb–Cu interactions to give a layered structure. In compound...

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Veröffentlicht in:Inorganic chemistry 2014-05, Vol.53 (10), p.4856-4860
Hauptverfasser: Zhang, Chi, Ji, Min, Ji, Shou-Hua, An, Yong-Lin
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container_title Inorganic chemistry
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creator Zhang, Chi
Ji, Min
Ji, Shou-Hua
An, Yong-Lin
description The new copper thioantimonates(III) and thioarsenate(III) Rb2Cu2Sb2S5 (1), Cs2Cu2Sb2S5 (2), and Rb8Cu6As8S19 (3) have been synthesized solvothermally. Compound 1 contains a [Cu2SbS3] net to which [Sb2S4] chains adhere through Cu–S bonds and Sb–Cu interactions to give a layered structure. In compound 2, the layer is formed by edge-sharing tetrahedral CuS4 chains linked by dimeric [Sb2S5] units. The layered structure in compound 3 is constructed by helical chains built from [Cu3S7] moieties and dimeric [As2S5] units which are further connected by tetrameric [As4S9] groups. Their optical and thermal properties have been investigated.
doi_str_mv 10.1021/ic402864s
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