Solvent-Dependent Decarboxylation of 1,3-Dimethylimdazolium-2‑Carboxylate

1,3-Dimethylimidazolium-2-carboxylate 1 is stable in both pure water and pure acetonitrile. However, in mixtures of the two solvents, this compound suffers a rapid decarboxylation/protonaton reaction, forming 1,3-dimethylimidazolium cation 2. A series of kinetic and mechanistic experiments, along wi...

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Veröffentlicht in:	Journal of organic chemistry 2014-05, Vol.79 (10), p.4293-4299
Hauptverfasser:	Denning, Derek M, Falvey, Daniel E
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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