Thiophene-Fused Borepins As Directly Functionalizable Boron-Containing π‑Electron Systems

Synthetic protocols were developed for the gram-scale preparation of two isomeric dithienoborepins (DTBs), boron-containing polycyclic aromatics featuring the fusion of borepin and thiophene rings. DTBs exhibit reversible cathodic electrochemistry and boron-centered Lewis acidity in addition to enha...

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Veröffentlicht in:Journal of the American Chemical Society 2014-05, Vol.136 (19), p.7132-7139
Hauptverfasser: Levine, David R, Siegler, Maxime A, Tovar, John D
Format: Artikel
Sprache:eng
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