NHC-Containing Manganese(I) Electrocatalysts for the Two-Electron Reduction of CO2

The synthesis and characterization of the first catalytic manganese N‐heterocyclic carbene complexes are reported: MnBr(N‐methyl‐N′‐2‐pyridylbenzimidazol‐2‐ylidine)(CO)3 and MnBr(N‐methyl‐N′‐2‐pyridylimidazol‐2‐ylidine)(CO)3. Both new species mediate the reduction of CO2 to CO following two‐electron...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-05, Vol.53 (20), p.5152-5155
Hauptverfasser:	Agarwal, Jay, Shaw, Travis W., Stanton III, Charles J., Majetich, George F., Bocarsly, Andrew B., Schaefer III, Henry F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Carbon monoxide catalysis Chemical reduction Chemical synthesis Electrocatalysts electrochemistry Electrolysis Electrons Manganese N-heterocyclic carbenes New species
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