Modeling Biological Copper Clusters: Synthesis of a Tricopper Complex, and Its Chloride- and Sulfide-Bridged Congeners

The synthesis and characterization of a family of tricopper clusters housed within a tris(β-diketimine) cyclophane ligand (H3 L) that bear structural similarities to biological copper clusters are reported. In all complexes, each Cu atom is held within the N2-chelate of a single β-diketiminate arm....

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Inorganic chemistry 2014-05, Vol.53 (9), p.4647-4654
Hauptverfasser:	Di Francesco, Gianna N, Gaillard, Aleth, Ghiviriga, Ion, Abboud, Khalil A, Murray, Leslie J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chlorides - chemistry Copper - chemistry Electron Spin Resonance Spectroscopy Models, Molecular Sulfides - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!