The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization

The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization

We report a joint photoelectron spectroscopic and theoretical study of the PtAl(-) and PtAl2(-) anions. The ground state structures and electronic configurations of these species were identified to be C∞v, (1)Σ(+) for PtAl(-), and C2v, (2)B1 for PtAl2(-). Structured anion photoelectron spectra of th...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 2014-04, Vol.140 (16), p.164316-164316
Hauptverfasser: Zhang, Xinxing, Ganteför, Gerd, Bowen, Kit H, Alexandrova, Anastassia N
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Electron transitions
Ground state
Physics
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 164316
container_issue 16
container_start_page 164316
container_title The Journal of chemical physics
container_volume 140
creator Zhang, Xinxing
Ganteför, Gerd
Bowen, Kit H
Alexandrova, Anastassia N
description We report a joint photoelectron spectroscopic and theoretical study of the PtAl(-) and PtAl2(-) anions. The ground state structures and electronic configurations of these species were identified to be C∞v, (1)Σ(+) for PtAl(-), and C2v, (2)B1 for PtAl2(-). Structured anion photoelectron spectra of these clusters were recorded and interpreted using ab initio calculations. Good agreement between theory and experiment was found. All experimental features were successfully assigned to one-electron transitions from the ground state of the anions to the ground or excited states of the corresponding neutral species.
doi_str_mv 10.1063/1.4873160
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1521330955</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2127665308</sourcerecordid><originalsourceid>FETCH-LOGICAL-c348t-991f625104f6c6b2da0e932c404911e6722e8b40f2e496b65293928a6a4a47d13</originalsourceid><addsrcrecordid>eNpdkD9PwzAQxS0EglIY-AIoEks7pNzZjhOzVRX_pEowlBFFjuOoqdI42M4An57QFgameyf97uneI-QKYYYg2C3OeJYyFHBERgiZjFMh4ZiMACjGUoA4I-febwAAU8pPyRnlacZpKkfkfbU20WuYN5N4Gqm23Gm6X2rb-rsorI11JtRaNTugW9tgTWN0cLaNfLcTXtuu1pFeK6d0MK7-UmE4vyAnlWq8uTzMMXl7uF8tnuLly-PzYr6MNeNZiKXEStAEgVdCi4KWCoxkVHPgEtGIlFKTFRwqargUhUioZJJmSiiueFoiG5PJ3rdz9qM3PuTb2mvTNKo1tvc5JhQZA5kkA3rzD93Y3rXDdzlFmgqRMMgGarqn9JDNO1Plnau3yn3mCPlP5znmh84H9vrg2BdbU_6RvyWzb6YMeJg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2127665308</pqid></control><display><type>article</type><title>The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Zhang, Xinxing ; Ganteför, Gerd ; Bowen, Kit H ; Alexandrova, Anastassia N</creator><creatorcontrib>Zhang, Xinxing ; Ganteför, Gerd ; Bowen, Kit H ; Alexandrova, Anastassia N</creatorcontrib><description>We report a joint photoelectron spectroscopic and theoretical study of the PtAl(-) and PtAl2(-) anions. The ground state structures and electronic configurations of these species were identified to be C∞v, (1)Σ(+) for PtAl(-), and C2v, (2)B1 for PtAl2(-). Structured anion photoelectron spectra of these clusters were recorded and interpreted using ab initio calculations. Good agreement between theory and experiment was found. All experimental features were successfully assigned to one-electron transitions from the ground state of the anions to the ground or excited states of the corresponding neutral species.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.4873160</identifier><identifier>PMID: 24784279</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>Anions ; Electron transitions ; Ground state ; Physics</subject><ispartof>The Journal of chemical physics, 2014-04, Vol.140 (16), p.164316-164316</ispartof><rights>2014 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-991f625104f6c6b2da0e932c404911e6722e8b40f2e496b65293928a6a4a47d13</citedby><cites>FETCH-LOGICAL-c348t-991f625104f6c6b2da0e932c404911e6722e8b40f2e496b65293928a6a4a47d13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/24784279$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Xinxing</creatorcontrib><creatorcontrib>Ganteför, Gerd</creatorcontrib><creatorcontrib>Bowen, Kit H</creatorcontrib><creatorcontrib>Alexandrova, Anastassia N</creatorcontrib><title>The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>We report a joint photoelectron spectroscopic and theoretical study of the PtAl(-) and PtAl2(-) anions. The ground state structures and electronic configurations of these species were identified to be C∞v, (1)Σ(+) for PtAl(-), and C2v, (2)B1 for PtAl2(-). Structured anion photoelectron spectra of these clusters were recorded and interpreted using ab initio calculations. Good agreement between theory and experiment was found. All experimental features were successfully assigned to one-electron transitions from the ground state of the anions to the ground or excited states of the corresponding neutral species.</description><subject>Anions</subject><subject>Electron transitions</subject><subject>Ground state</subject><subject>Physics</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpdkD9PwzAQxS0EglIY-AIoEks7pNzZjhOzVRX_pEowlBFFjuOoqdI42M4An57QFgameyf97uneI-QKYYYg2C3OeJYyFHBERgiZjFMh4ZiMACjGUoA4I-febwAAU8pPyRnlacZpKkfkfbU20WuYN5N4Gqm23Gm6X2rb-rsorI11JtRaNTugW9tgTWN0cLaNfLcTXtuu1pFeK6d0MK7-UmE4vyAnlWq8uTzMMXl7uF8tnuLly-PzYr6MNeNZiKXEStAEgVdCi4KWCoxkVHPgEtGIlFKTFRwqargUhUioZJJmSiiueFoiG5PJ3rdz9qM3PuTb2mvTNKo1tvc5JhQZA5kkA3rzD93Y3rXDdzlFmgqRMMgGarqn9JDNO1Plnau3yn3mCPlP5znmh84H9vrg2BdbU_6RvyWzb6YMeJg</recordid><startdate>20140428</startdate><enddate>20140428</enddate><creator>Zhang, Xinxing</creator><creator>Ganteför, Gerd</creator><creator>Bowen, Kit H</creator><creator>Alexandrova, Anastassia N</creator><general>American Institute of Physics</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20140428</creationdate><title>The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization</title><author>Zhang, Xinxing ; Ganteför, Gerd ; Bowen, Kit H ; Alexandrova, Anastassia N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-991f625104f6c6b2da0e932c404911e6722e8b40f2e496b65293928a6a4a47d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Anions</topic><topic>Electron transitions</topic><topic>Ground state</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xinxing</creatorcontrib><creatorcontrib>Ganteför, Gerd</creatorcontrib><creatorcontrib>Bowen, Kit H</creatorcontrib><creatorcontrib>Alexandrova, Anastassia N</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xinxing</au><au>Ganteför, Gerd</au><au>Bowen, Kit H</au><au>Alexandrova, Anastassia N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization</atitle><jtitle>The Journal of chemical physics</jtitle><addtitle>J Chem Phys</addtitle><date>2014-04-28</date><risdate>2014</risdate><volume>140</volume><issue>16</issue><spage>164316</spage><epage>164316</epage><pages>164316-164316</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>We report a joint photoelectron spectroscopic and theoretical study of the PtAl(-) and PtAl2(-) anions. The ground state structures and electronic configurations of these species were identified to be C∞v, (1)Σ(+) for PtAl(-), and C2v, (2)B1 for PtAl2(-). Structured anion photoelectron spectra of these clusters were recorded and interpreted using ab initio calculations. Good agreement between theory and experiment was found. All experimental features were successfully assigned to one-electron transitions from the ground state of the anions to the ground or excited states of the corresponding neutral species.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>24784279</pmid><doi>10.1063/1.4873160</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 2014-04, Vol.140 (16), p.164316-164316
issn 0021-9606
1089-7690
language eng
recordid cdi_proquest_miscellaneous_1521330955
source AIP Journals Complete; Alma/SFX Local Collection
subjects Anions
Electron transitions
Ground state
Physics
title The PtAl(-) and PtAl2(-) anions: theoretical and photoelectron spectroscopic characterization
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T17%3A24%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20PtAl(-)%20and%20PtAl2(-)%20anions:%20theoretical%20and%20photoelectron%20spectroscopic%20characterization&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Zhang,%20Xinxing&rft.date=2014-04-28&rft.volume=140&rft.issue=16&rft.spage=164316&rft.epage=164316&rft.pages=164316-164316&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.4873160&rft_dat=%3Cproquest_cross%3E2127665308%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2127665308&rft_id=info:pmid/24784279&rfr_iscdi=true