Borohydride-Mediated Radical Addition Reactions of Organic Iodides to Electron-Deficient Alkenes

Cyanoborohydrides are efficient reagents in the reductive addition reactions of alkyl iodides and electron-deficient olefins. In contrast to using tin reagents, the reaction took place chemoselectively at the carbon–iodine bond but not at the carbon–bromine or carbon–chlorine bond. The reaction syst...

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Veröffentlicht in:	Journal of organic chemistry 2014-05, Vol.79 (9), p.3999-4007
Hauptverfasser:	Kawamoto, Takuji, Uehara, Shohei, Hirao, Hidefumi, Fukuyama, Takahide, Matsubara, Hiroshi, Ryu, Ilhyong
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Borohydrides - chemistry Electrons Free Radicals - chemistry Hydrocarbons, Iodinated - chemistry Molecular Structure
Online-Zugang:	Volltext
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