Carborane complexes of ruthenium with long-chain diphosphine ligands as effective catalysts of controlled radical polymerization

Catalytic systems based on carborane complexes of ruthenium with long-chain diphosphine ligands, such as 1,4-bis(diphenylphosphino)butane and 1,5-bis(diphenylphosphino)pentane, are prepared for the controlled radical polymerization of methyl methacrylate. It is found that the used metallacarboranes...

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Veröffentlicht in:Polymer science. Series B 2014, Vol.56 (1), p.1-10
Hauptverfasser: Grishin, I. D., Turmina, E. S., D’yachihin, D. I., Chizhevsky, I. T., Grishin, D. F.
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Sprache:eng
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