Spectroscopic Study of Proflavine Adsorption on the Carbon Nanotube Surface

Despite the fact that non-covalent interactions between various aromatic compounds and carbon nanotubes are being extensively investigated now, there is still a lack of understanding about the nature of such interactions. The present paper sheds light on one of the possible mechanisms of interaction...

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Veröffentlicht in:Applied spectroscopy 2014-02, Vol.68 (2), p.232-237
Hauptverfasser: Buchelnikov, Anatoly S., Dovbeshko, Galina I., Voronin, Dmitry P., Trachevsky, Vladimir V., Kostjukov, Viktor V., Evstigneev, Maxim P.
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container_end_page 237
container_issue 2
container_start_page 232
container_title Applied spectroscopy
container_volume 68
creator Buchelnikov, Anatoly S.
Dovbeshko, Galina I.
Voronin, Dmitry P.
Trachevsky, Vladimir V.
Kostjukov, Viktor V.
Evstigneev, Maxim P.
description Despite the fact that non-covalent interactions between various aromatic compounds and carbon nanotubes are being extensively investigated now, there is still a lack of understanding about the nature of such interactions. The present paper sheds light on one of the possible mechanisms of interaction between the typical aromatic dye proflavine and the carbon nanotube surface, namely, π-stacking between aromatic rings of these compounds. To investigate such a complexation, a qualitative analysis was performed by means of ultraviolet visible, infrared, and nuclear magnetic resonance spectroscopy. The data obtained suggest that π-stacking brings the major contribution to the stabilization of the complex between proflavine and the carbon nanotube.
doi_str_mv 10.1366/13-07205
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subjects Adsorption
Aromatic compounds
Carbon nanotubes
Complexation
Dyes
Infrared
Magnetic Resonance Spectroscopy - methods
Models, Molecular
Nanotubes, Carbon - chemistry
Proflavine - chemistry
Spectrophotometry, Ultraviolet - methods
Spectroscopy
Stabilization
Surface chemistry
title Spectroscopic Study of Proflavine Adsorption on the Carbon Nanotube Surface
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