Double-hydrophobic siloxane diblock copolymers: Synthesis, micellization behavior, and application as a stabilizer for silver nanoparticles
The double‐hydrophobic well‐defined polydimethylsiloxane‐block‐poly(methyl methacrylate) (PDMS‐b‐PMMA) diblock copolymers were synthesized via atom transfer radical polymerization (ATRP). Their chemical compositions and the structure were investigated. The micellization behavior of the double‐hydrop...
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| Veröffentlicht in: | Polymer engineering and science 2013-07, Vol.53 (7), p.1475-1486 |
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| container_title | Polymer engineering and science |
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| creator | Zhou, Hong-Ming Cheng, Hua Luo, Zheng-Hong |
| description | The double‐hydrophobic well‐defined polydimethylsiloxane‐block‐poly(methyl methacrylate) (PDMS‐b‐PMMA) diblock copolymers were synthesized via atom transfer radical polymerization (ATRP). Their chemical compositions and the structure were investigated. The micellization behavior of the double‐hydrophobic diblock copolymers with equal block length was thoroughly studied. The results showed that their self‐assembly behavior was analogous to the star‐like micelles. Furthermore, the effect of temperature on the aggregates was investigated to verify that the resulting copolymer (PDMS‐b‐PMMA) was to some extent temperature sensitive. Till date, there have been few reports on the utilization of nonamphiphilic block copolymers to synthesize and confine metal nanoparticles in aggregates. In this study, we explored the role of double‐hydrophobic block copolymers as a mediator for organically dispersible silver nanoparticles (AgNPs) and it offered to be an effective stabilizer for preparing AgNPs. Besides, AgNPs generated in organic solvent is an important addition to the hitherto predominantly water‐based processes for producing nanoparticles inside the polymer surfactant. POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.23400 |
| format | Article |
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Their chemical compositions and the structure were investigated. The micellization behavior of the double‐hydrophobic diblock copolymers with equal block length was thoroughly studied. The results showed that their self‐assembly behavior was analogous to the star‐like micelles. Furthermore, the effect of temperature on the aggregates was investigated to verify that the resulting copolymer (PDMS‐b‐PMMA) was to some extent temperature sensitive. Till date, there have been few reports on the utilization of nonamphiphilic block copolymers to synthesize and confine metal nanoparticles in aggregates. In this study, we explored the role of double‐hydrophobic block copolymers as a mediator for organically dispersible silver nanoparticles (AgNPs) and it offered to be an effective stabilizer for preparing AgNPs. Besides, AgNPs generated in organic solvent is an important addition to the hitherto predominantly water‐based processes for producing nanoparticles inside the polymer surfactant. 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Their chemical compositions and the structure were investigated. The micellization behavior of the double‐hydrophobic diblock copolymers with equal block length was thoroughly studied. The results showed that their self‐assembly behavior was analogous to the star‐like micelles. Furthermore, the effect of temperature on the aggregates was investigated to verify that the resulting copolymer (PDMS‐b‐PMMA) was to some extent temperature sensitive. Till date, there have been few reports on the utilization of nonamphiphilic block copolymers to synthesize and confine metal nanoparticles in aggregates. In this study, we explored the role of double‐hydrophobic block copolymers as a mediator for organically dispersible silver nanoparticles (AgNPs) and it offered to be an effective stabilizer for preparing AgNPs. Besides, AgNPs generated in organic solvent is an important addition to the hitherto predominantly water‐based processes for producing nanoparticles inside the polymer surfactant. 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SCI., 2013. © 2012 Society of Plastics Engineers</description><subject>Aggregates</subject><subject>Applied sciences</subject><subject>Block copolymers</subject><subject>Chemical modifications</subject><subject>Chemical processes</subject><subject>Chemical properties</subject><subject>Composition</subject><subject>Copolymers</subject><subject>Exact sciences and technology</subject><subject>Hydrophobicity</subject><subject>Inorganic and organomineral polymers</subject><subject>Nanoparticles</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Polymethylmethacrylate</subject><subject>Production processes</subject><subject>Radicals</subject><subject>Self assembly</subject><subject>Siloxanes</subject><subject>Silver</subject><subject>Solvents</subject><subject>Surfactants</subject><subject>Temperature effects</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNp1kt9uFCEUxidGE9fqhW8wiTHRZGcLA8ww3rW11iZNNdY_vSMMc9ilZWGE2dr1FXxpWXetrllDAifw-z44h5NlTzGaYITK_R7cpCQUoXvZCDPKi7Ii9H42QoiUBeGcP8wexXiFEktYM8p-vPaL1kIxW3bB9zPfGpVHY_2tdJB3prVeXefK994u5xDiq_xi6YYZRBPH-dwosNZ8l4PxLm9hJm-MD-Ncui6XfW-NWp_ImMs8DrI1CYaQax9Wd9yk0EnnexkGoyzEx9kDLW2EJ5t1L_v05vjj0dvi7N3J6dHBWaFYTVHRtIBBMkw1VTVoBW0DimiNGe_KusSdxpWWCjVVSyrUdRxTiihQUrIKcajJXvZi7dsH_3UBcRBzE1eppJz9IgrMStRQXPEqoc_-Qa_8Irj0OoFpU1W0qgn9Q02lBWGc9kOQamUqDgipcMM444kqdlBTcBCk9Q60Sdtb_GQHn0YHqfI7BS-3BIkZ4HaYykWM4vTiwzY7_ottF9E4iGmKZjob4lqyy1oFH2MALfpg5jIsBUZi1XgiNZ741XiJfb6pmYxKWh2kUybeCcqaIU44S9z-mvuW8lj-31C8Pz7_7bypoIkpsTuFDNci_UPNxJfzE3FJysvq8-FhCn4C6IT1lg</recordid><startdate>201307</startdate><enddate>201307</enddate><creator>Zhou, Hong-Ming</creator><creator>Cheng, Hua</creator><creator>Luo, Zheng-Hong</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>201307</creationdate><title>Double-hydrophobic siloxane diblock copolymers: Synthesis, micellization behavior, and application as a stabilizer for silver nanoparticles</title><author>Zhou, Hong-Ming ; 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Their chemical compositions and the structure were investigated. The micellization behavior of the double‐hydrophobic diblock copolymers with equal block length was thoroughly studied. The results showed that their self‐assembly behavior was analogous to the star‐like micelles. Furthermore, the effect of temperature on the aggregates was investigated to verify that the resulting copolymer (PDMS‐b‐PMMA) was to some extent temperature sensitive. Till date, there have been few reports on the utilization of nonamphiphilic block copolymers to synthesize and confine metal nanoparticles in aggregates. In this study, we explored the role of double‐hydrophobic block copolymers as a mediator for organically dispersible silver nanoparticles (AgNPs) and it offered to be an effective stabilizer for preparing AgNPs. Besides, AgNPs generated in organic solvent is an important addition to the hitherto predominantly water‐based processes for producing nanoparticles inside the polymer surfactant. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aggregates Applied sciences Block copolymers Chemical modifications Chemical processes Chemical properties Composition Copolymers Exact sciences and technology Hydrophobicity Inorganic and organomineral polymers Nanoparticles Physicochemistry of polymers Polymerization Polymethylmethacrylate Production processes Radicals Self assembly Siloxanes Silver Solvents Surfactants Temperature effects |
| title | Double-hydrophobic siloxane diblock copolymers: Synthesis, micellization behavior, and application as a stabilizer for silver nanoparticles |
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