Cooperative Effect of Two Metals: CoPd(OAc)4-Catalyzed CH Amination and Aziridination

The first Co/Pd‐cocatalyzed intramolecular CH amination and aziridination reactions were developed. Sulfamate esters were converted to oxathiazinanes by using CoPd(OAc)4 as catalyst and PhI(OAc)2 as oxidant. The mutual presence of both Co and Pd is crucial for the catalytic activity. This combinati...

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Veröffentlicht in:Chemistry : a European journal 2014-04, Vol.20 (18), p.5240-5243
Hauptverfasser: Huang, Guan-Hao, Li, Jian-Min, Huang, Jing-Jyun, Lin, Jyun-Dai, Chuang, Gary Jing
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Sprache:eng
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